Efficient Base-Free Hydrogenation of Amides to Alcohols and Amines Catalyzed by Well-Defined Pincer Imidazolyl–Ruthenium Complexes

Novel homogeneous ruthenium catalysts bearing an imidazolylaminophosphino pincer ligand have been synthesized. The active catalyst allows for the hydrogenation of a range of amides under base-free conditions to afford the corresponding alcohols and amines in high yields.

Detalles Bibliográficos
Autores: Cabrero-Antonino, José Ramón, Alberico, Elisabetta, Drexler, Hans-Joachim, Baumann, Wolfgang, Junge, Kathrin, Junge, Henrik, Beller, Matthias
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2015
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/375632
Acceso en línea:http://hdl.handle.net/10261/375632
Access Level:acceso abierto
Palabra clave:amide hydrogenation
ruthenium
bifunctional catalysis
pincer complexes
homogeneous catalysis
id ES_9c331a2669ae6632ed85f790c06a56be
oai_identifier_str oai:digital.csic.es:10261/375632
network_acronym_str ES
network_name_str España
repository_id_str
spelling Efficient Base-Free Hydrogenation of Amides to Alcohols and Amines Catalyzed by Well-Defined Pincer Imidazolyl–Ruthenium ComplexesCabrero-Antonino, José RamónAlberico, ElisabettaDrexler, Hans-JoachimBaumann, WolfgangJunge, KathrinJunge, HenrikBeller, Matthiasamide hydrogenationrutheniumbifunctional catalysispincer complexeshomogeneous catalysisNovel homogeneous ruthenium catalysts bearing an imidazolylaminophosphino pincer ligand have been synthesized. The active catalyst allows for the hydrogenation of a range of amides under base-free conditions to afford the corresponding alcohols and amines in high yields.Peer reviewedACS PublicationsConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202520252015info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionhttp://hdl.handle.net/10261/375632reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Ingléshttps://pubs.acs.org/doi/10.1021/acscatal.5b01955Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3756322026-05-22T06:33:51Z
dc.title.none.fl_str_mv Efficient Base-Free Hydrogenation of Amides to Alcohols and Amines Catalyzed by Well-Defined Pincer Imidazolyl–Ruthenium Complexes
title Efficient Base-Free Hydrogenation of Amides to Alcohols and Amines Catalyzed by Well-Defined Pincer Imidazolyl–Ruthenium Complexes
spellingShingle Efficient Base-Free Hydrogenation of Amides to Alcohols and Amines Catalyzed by Well-Defined Pincer Imidazolyl–Ruthenium Complexes
Cabrero-Antonino, José Ramón
amide hydrogenation
ruthenium
bifunctional catalysis
pincer complexes
homogeneous catalysis
title_short Efficient Base-Free Hydrogenation of Amides to Alcohols and Amines Catalyzed by Well-Defined Pincer Imidazolyl–Ruthenium Complexes
title_full Efficient Base-Free Hydrogenation of Amides to Alcohols and Amines Catalyzed by Well-Defined Pincer Imidazolyl–Ruthenium Complexes
title_fullStr Efficient Base-Free Hydrogenation of Amides to Alcohols and Amines Catalyzed by Well-Defined Pincer Imidazolyl–Ruthenium Complexes
title_full_unstemmed Efficient Base-Free Hydrogenation of Amides to Alcohols and Amines Catalyzed by Well-Defined Pincer Imidazolyl–Ruthenium Complexes
title_sort Efficient Base-Free Hydrogenation of Amides to Alcohols and Amines Catalyzed by Well-Defined Pincer Imidazolyl–Ruthenium Complexes
dc.creator.none.fl_str_mv Cabrero-Antonino, José Ramón
Alberico, Elisabetta
Drexler, Hans-Joachim
Baumann, Wolfgang
Junge, Kathrin
Junge, Henrik
Beller, Matthias
author Cabrero-Antonino, José Ramón
author_facet Cabrero-Antonino, José Ramón
Alberico, Elisabetta
Drexler, Hans-Joachim
Baumann, Wolfgang
Junge, Kathrin
Junge, Henrik
Beller, Matthias
author_role author
author2 Alberico, Elisabetta
Drexler, Hans-Joachim
Baumann, Wolfgang
Junge, Kathrin
Junge, Henrik
Beller, Matthias
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv amide hydrogenation
ruthenium
bifunctional catalysis
pincer complexes
homogeneous catalysis
topic amide hydrogenation
ruthenium
bifunctional catalysis
pincer complexes
homogeneous catalysis
description Novel homogeneous ruthenium catalysts bearing an imidazolylaminophosphino pincer ligand have been synthesized. The active catalyst allows for the hydrogenation of a range of amides under base-free conditions to afford the corresponding alcohols and amines in high yields.
publishDate 2015
dc.date.none.fl_str_mv 2015
2025
2025
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Postprint
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/375632
url http://hdl.handle.net/10261/375632
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv https://pubs.acs.org/doi/10.1021/acscatal.5b01955
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv ACS Publications
publisher.none.fl_str_mv ACS Publications
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869414637245562880
score 15,223283

Similares en LA Referencia