Solution-sheared thin films of a donor-acceptor random copolymer/ polystyrene blend as active material in field-effect transistors
Organic semiconductor (OSC):polymer blends are recently increasing their popularity due to the impressive performances they offer once employed as active layer in organic field-effect transistors (OFETs). Here a novel blend formulation composed by the donor-acceptor random copolymer PDPP-TT(1)-SVS(9...
| Autores: | , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2019 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/175004 |
| Acceso en línea: | http://hdl.handle.net/10261/175004 |
| Access Level: | acceso abierto |
| Palabra clave: | Electrolytes Organic field effect transistors Phase separation Polymer blends Shearing Thin film transistors Thin films Ambient conditions Device performance Device stability Donor acceptors Morphological properties Random copolymer Solution shearing Vertical phase separations Thin film circuits |
| Sumario: | Organic semiconductor (OSC):polymer blends are recently increasing their popularity due to the impressive performances they offer once employed as active layer in organic field-effect transistors (OFETs). Here a novel blend formulation composed by the donor-acceptor random copolymer PDPP-TT(1)-SVS(9) and polystyrene has been processed by a solution shearing technique and employed as active material in a thin film transistor. The molecular weight of the polymer binder has revealed to be fundamental for controlling the vertical phase separation and, in turn, for determining the morphological properties of the upper surface which is critical in terms of device stability. The bi-component active layer has been tested as OFET and by using a top gate as electrolyte-gated field-effect transistor (EGOFET). Our strategy based on an OSC:polymer blend processed through a solution shearing technique has demonstrated to be efficient for improving the final device performance in ambient conditions. |
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