The influence of crystallization route on the SrBi2Nb2O9 thin films

Polycrystalline SrBi2Nb2O9-layered ferroelectric thin films were synthesized on Pt/Ti/SiO2/Si substrate using the polymeric precursors solution. The dip-coated films were specular and crack-free and crystallized during firing at 700 °C. Single-, double-, and triple-layered films were obtained by sev...

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Detalhes bibliográficos
Autores: Zanetti, S. M., Leite, E. R., Longo, Elson [UNESP], Varela, José Arana [UNESP]
Formato: artículo
Estado:Versión publicada
Fecha de publicación:1999
País:Brasil
Recursos:Universidade Estadual Paulista (UNESP)
Repositorio:Repositório Institucional da UNESP
Idioma:inglés
OAI Identifier:oai:repositorio.unesp.br:11449/65732
Acesso em linha:http://dx.doi.org/10.1557/JMR.1999.0136
http://hdl.handle.net/11449/65732
Access Level:acceso abierto
Palavra-chave:Crystal microstructure
Crystal orientation
Crystallization
Deposition
Ferroelectric materials
Grain size and shape
Morphology
Multilayers
Perovskite
Polycrystalline materials
Strontium compounds
Synthesis (chemical)
Grazing incident X ray diffraction (GIXRD) analysis
Dielectric films
Descrição
Resumo:Polycrystalline SrBi2Nb2O9-layered ferroelectric thin films were synthesized on Pt/Ti/SiO2/Si substrate using the polymeric precursors solution. The dip-coated films were specular and crack-free and crystallized during firing at 700 °C. Single-, double-, and triple-layered films were obtained by several dips in the deposition solution, and the influence of crystallization between each dip was studied. Microstructure and morphological evaluation were followed by grazing incident x-ray diffraction (GIXRD), scanning electron microscopy (SEM), and atomic force microscopy (AFM). Multilayered films obtained using the intermediate-crystallized layer route present a dense microstructure with spherical grains, with a preferential orientation in the 〈215〉 direction; films obtained using the intermediate-amorphous layer route are polycrystalline and present elongated grains around 250 nm in size.