Synthesis of multicyclic β-Lactam derivatives via solid-phase- generated ketenes

An efficient approach for the solid-phase synthesis of multicyclic â-lactam derivatives is described. The key step is the cycloaddition reaction between an immobilized ketene and different cyclic imines to afford the corresponding benzofused carbacepham derivatives in high yield for the overall synt...

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Detalhes bibliográficos
Autores: Mendez, Luciana, Mata, Ernesto Gabino
Tipo de documento: artigo
Estado:Versão publicada
Data de publicação:2010
País:Argentina
Recursos:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositório:CONICET Digital (CONICET)
Idioma:inglês
OAI Identifier:oai:ri.conicet.gov.ar:11336/127696
Acesso em linha:http://hdl.handle.net/11336/127696
Access Level:Acceso aberto
Palavra-chave:solid-phase synthesis
beta-lactam derivatives
staudinger cycloaddition
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
Descrição
Resumo:An efficient approach for the solid-phase synthesis of multicyclic â-lactam derivatives is described. The key step is the cycloaddition reaction between an immobilized ketene and different cyclic imines to afford the corresponding benzofused carbacepham derivatives in high yield for the overall synthetic sequence.