Solid-supported cross-metathesis and a formal alkane metathesis for the generation of biologically relevant molecules

Solid-phase synthetic strategies towards the generation of libraries of biologically relevant molecules were developed using olefin cross-metathesis as a key step. It is remarkably the formal alkane metathesis based on a one-pot, microwave-assisted, ruthenium catalyzed cross-metathesis and reduction...

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Detalhes bibliográficos
Autores: Mendez, Luciana, Mata, Ernesto Gabino
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2015
País:Argentina
Recursos:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/6067
Acesso em linha:http://hdl.handle.net/11336/6067
Access Level:acceso abierto
Palavra-chave:Olefin Metathesis
Solid-Phase Organic Synthesis
Chalcones
Microwave Heating
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
Descrição
Resumo:Solid-phase synthetic strategies towards the generation of libraries of biologically relevant molecules were developed using olefin cross-metathesis as a key step. It is remarkably the formal alkane metathesis based on a one-pot, microwave-assisted, ruthenium catalyzed cross-metathesis and reduction to obtain Csp3-Csp3 linkages