Spectroscopic and Microscopic Characterization of Volcanic Ash from Puyehue-(Chile) Eruption: Preliminary Approach for the Application in the Arsenic Removal
Volcanic ash fromPuyehueCordonCaulleVolcanicComplex (Chile), emitted on June 4, 2011, and deposited inVilla LaAngostura at ∼40 kmof the source, was collected and analyzed by Raman spectroscopy, optical and scanning electron microscopy (SEM-EDS), Xray diffraction (XRD), surface area (BET), and chemic...
| Autores: | , , , |
|---|---|
| Tipo de documento: | artigo |
| Estado: | Versão publicada |
| Data de publicação: | 2013 |
| País: | Argentina |
| Recursos: | Comisión de Investigaciones Científicas de la Provincia de Buenos Aires |
| Repositório: | CIC Digital (CICBA) |
| Idioma: | inglês |
| OAI Identifier: | oai:digital.cic.gba.gob.ar:11746/7080 |
| Acesso em linha: | https://digital.cic.gba.gob.ar/handle/11746/7080 |
| Access Level: | Acceso aberto |
| Palavra-chave: | Ciencias Químicas volcanic ash physicochemical study themineralogical study iron arsenic |
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Spectroscopic and Microscopic Characterization of Volcanic Ash from Puyehue-(Chile) Eruption: Preliminary Approach for the Application in the Arsenic RemovalBotto, Irma LíaCanafoglia, María ElenaGazzoli, DeliaGonzález, María JoséCiencias Químicasvolcanic ashphysicochemical studythemineralogical studyironarsenicVolcanic ash fromPuyehueCordonCaulleVolcanicComplex (Chile), emitted on June 4, 2011, and deposited inVilla LaAngostura at ∼40 kmof the source, was collected and analyzed by Raman spectroscopy, optical and scanning electron microscopy (SEM-EDS), Xray diffraction (XRD), surface area (BET), and chemical analysis (ICP-AES-MS technique).Themineralogical and physicochemical study revealed that the pyroclastic mixture contains iron oxides in the form of magnetite and hematite as well as pyroxene and plagioclase mineral species and amorphous pumiceous shards. Carbonaceous material was also identified. Physicochemical techniques allow us to select two representative samples (average composition and Fe-rich materials) which were used to analyze their performances in the adsorption process to remove arsenic from water. Additional iron activation by means of ferric salts was performed under original sample. Results showed that the low-cost feedstock exhibited a good adsorption capacity to remove the contaminant, depending on the iron content and the water pH.Hindawi Publishing Corporation2013info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttps://digital.cic.gba.gob.ar/handle/11746/7080enginfo:eu-repo/semantics/altIdentifier/doi/10.1155/2013/254517info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/reponame:CIC Digital (CICBA)instname:Comisión de Investigaciones Científicas de la Provincia de Buenos Airesinstacron:CICBA2024-05-10T10:39:19Zoai:digital.cic.gba.gob.ar:11746/7080Institucionalhttp://digital.cic.gba.gob.arOrganismo científico-tecnológicoNo correspondehttp://digital.cic.gba.gob.ar/oai/snrdmarisa.degiusti@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:94412024-05-10 10:39:19.441CIC Digital (CICBA) - Comisión de Investigaciones Científicas de la Provincia de Buenos Airesfalse |
| dc.title.none.fl_str_mv |
Spectroscopic and Microscopic Characterization of Volcanic Ash from Puyehue-(Chile) Eruption: Preliminary Approach for the Application in the Arsenic Removal |
| title |
Spectroscopic and Microscopic Characterization of Volcanic Ash from Puyehue-(Chile) Eruption: Preliminary Approach for the Application in the Arsenic Removal |
| spellingShingle |
Spectroscopic and Microscopic Characterization of Volcanic Ash from Puyehue-(Chile) Eruption: Preliminary Approach for the Application in the Arsenic Removal Botto, Irma Lía Ciencias Químicas volcanic ash physicochemical study themineralogical study iron arsenic |
| title_short |
Spectroscopic and Microscopic Characterization of Volcanic Ash from Puyehue-(Chile) Eruption: Preliminary Approach for the Application in the Arsenic Removal |
| title_full |
Spectroscopic and Microscopic Characterization of Volcanic Ash from Puyehue-(Chile) Eruption: Preliminary Approach for the Application in the Arsenic Removal |
| title_fullStr |
Spectroscopic and Microscopic Characterization of Volcanic Ash from Puyehue-(Chile) Eruption: Preliminary Approach for the Application in the Arsenic Removal |
| title_full_unstemmed |
Spectroscopic and Microscopic Characterization of Volcanic Ash from Puyehue-(Chile) Eruption: Preliminary Approach for the Application in the Arsenic Removal |
| title_sort |
Spectroscopic and Microscopic Characterization of Volcanic Ash from Puyehue-(Chile) Eruption: Preliminary Approach for the Application in the Arsenic Removal |
| dc.creator.none.fl_str_mv |
Botto, Irma Lía Canafoglia, María Elena Gazzoli, Delia González, María José |
| author |
Botto, Irma Lía |
| author_facet |
Botto, Irma Lía Canafoglia, María Elena Gazzoli, Delia González, María José |
| author_role |
author |
| author2 |
Canafoglia, María Elena Gazzoli, Delia González, María José |
| author2_role |
author author author |
| dc.subject.none.fl_str_mv |
Ciencias Químicas volcanic ash physicochemical study themineralogical study iron arsenic |
| topic |
Ciencias Químicas volcanic ash physicochemical study themineralogical study iron arsenic |
| description |
Volcanic ash fromPuyehueCordonCaulleVolcanicComplex (Chile), emitted on June 4, 2011, and deposited inVilla LaAngostura at ∼40 kmof the source, was collected and analyzed by Raman spectroscopy, optical and scanning electron microscopy (SEM-EDS), Xray diffraction (XRD), surface area (BET), and chemical analysis (ICP-AES-MS technique).Themineralogical and physicochemical study revealed that the pyroclastic mixture contains iron oxides in the form of magnetite and hematite as well as pyroxene and plagioclase mineral species and amorphous pumiceous shards. Carbonaceous material was also identified. Physicochemical techniques allow us to select two representative samples (average composition and Fe-rich materials) which were used to analyze their performances in the adsorption process to remove arsenic from water. Additional iron activation by means of ferric salts was performed under original sample. Results showed that the low-cost feedstock exhibited a good adsorption capacity to remove the contaminant, depending on the iron content and the water pH. |
| publishDate |
2013 |
| dc.date.none.fl_str_mv |
2013 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
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article |
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publishedVersion |
| dc.identifier.none.fl_str_mv |
https://digital.cic.gba.gob.ar/handle/11746/7080 |
| url |
https://digital.cic.gba.gob.ar/handle/11746/7080 |
| dc.language.none.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1155/2013/254517 |
| dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/4.0/ |
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openAccess |
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http://creativecommons.org/licenses/by/4.0/ |
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application/pdf |
| dc.publisher.none.fl_str_mv |
Hindawi Publishing Corporation |
| publisher.none.fl_str_mv |
Hindawi Publishing Corporation |
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reponame:CIC Digital (CICBA) instname:Comisión de Investigaciones Científicas de la Provincia de Buenos Aires instacron:CICBA |
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Comisión de Investigaciones Científicas de la Provincia de Buenos Aires |
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CICBA |
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CICBA |
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CIC Digital (CICBA) |
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CIC Digital (CICBA) |
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CIC Digital (CICBA) - Comisión de Investigaciones Científicas de la Provincia de Buenos Aires |
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marisa.degiusti@sedici.unlp.edu.ar |
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15.228081 |