Spectroscopic and Microscopic Characterization of Volcanic Ash from Puyehue-(Chile) Eruption: Preliminary Approach for the Application in the Arsenic Removal

Volcanic ash from Puyehue Cordon Caulle Volcanic Complex (Chile), emitted on June 4, 2011, and deposited inVilla LaAngostura at ∼40 kmof the source, was collected and analyzed by Raman spectroscopy, optical and scanning electron microscopy (SEM-EDS), Xray diffraction (XRD), surface area (BET), and c...

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Detalles Bibliográficos
Autores: Botto, Irma Lía, Canafoglia, María Elena, Gazzoli, Delia, González, María José
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2013
País:Argentina
Institución:Universidad Nacional de La Plata
Repositorio:SEDICI (UNLP)
Idioma:español
OAI Identifier:oai:sedici.unlp.edu.ar:10915/68073
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/68073
Access Level:acceso abierto
Palabra clave:Ciencias Exactas
volcanic ash, physicochemical study, themineralogical study, iron, arsenic
Minerales
Chile
Arsénico
Descripción
Sumario:Volcanic ash from Puyehue Cordon Caulle Volcanic Complex (Chile), emitted on June 4, 2011, and deposited inVilla LaAngostura at ∼40 kmof the source, was collected and analyzed by Raman spectroscopy, optical and scanning electron microscopy (SEM-EDS), Xray diffraction (XRD), surface area (BET), and chemical analysis (ICP-AES-MS technique).Themineralogical and physicochemical study revealed that the pyroclastic mixture contains iron oxides in the form of magnetite and hematite as well as pyroxene and plagioclase mineral species and amorphous pumiceous shards. Carbonaceous material was also identified. Physicochemical techniques allow us to select two representative samples (average composition and Fe-rich materials) which were used to analyze their performances in the adsorption process to remove arsenic from water. Additional iron activation by means of ferric salts was performed under original sample. Results showed that the low-cost feedstock exhibited a good adsorption capacity to remove the contaminant, depending on the iron content and the water pH.