4.A BET approach to multilayer adsorption in swelling products

An equation for multimolecular sorption is presented. It is based on the BET model with the assumption that the adsorbing surface can be divided in two regions: A region that supports only a limited number of adsorbed layers due to geometric restrictions, and another region that can adsorb an unlimi...

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Detalhes bibliográficos
Autores: Pantuso, F. S., Tolaba, Marcela Patricia, Aguerre, Roberto Jorge
Tipo de documento: artigo
Estado:Versão publicada
Data de publicação:2013
País:Argentina
Recursos:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositório:CONICET Digital (CONICET)
Idioma:inglês
OAI Identifier:oai:ri.conicet.gov.ar:11336/24863
Acesso em linha:http://hdl.handle.net/11336/24863
Access Level:Acceso aberto
Palavra-chave:Swelling
Water Adsorption
Porosity
Isotherm Shapes
Multilayer Adsorption
Free Energy of Adsorption
https://purl.org/becyt/ford/2.11
https://purl.org/becyt/ford/2
Descrição
Resumo:An equation for multimolecular sorption is presented. It is based on the BET model with the assumption that the adsorbing surface can be divided in two regions: A region that supports only a limited number of adsorbed layers due to geometric restrictions, and another region that can adsorb an unlimited number of layers. The proposed equation is applicable to type 2 and 3 isotherms (BDDT classification), and was successfully used to fit water sorption equilibrium data of some foodstuff from literature for the water activity range 0.05?0.90, and a temperature range from 10 to 70 C.