A combined method of neutron activation analysis and radiometric measurements for U-234 and U-238 determination in soil samples of low uranium concentration

A method that combines the use of non-destructive neutron activation analysis and high-resolution spectrometry has been developed for determination of the activities of U-234 and U-238 in geological samples of low uranium content. The U-238 content is determined by k0-based neutron activation analys...

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Bibliographic Details
Authors: Montoya, Eduardo, Baltuano, Oscar, Cohen, Isaac, Bedregal, Patricia, Mendoza, Pablo
Format: article
Publication Date:2011
Country:Perú
Institution:Instituto Peruano de Energía Nuclear
Repository:IPEN-Institucional
Language:English
OAI Identifier:oai:repositorio.ipen.gob.pe:20.500.13054/622
Online Access:https://hdl.handle.net/20.500.13054/622
Access Level:Open access
Keyword:Análisis por activación neutrónica
Análisis radiométrico
Uranio 234
Uranio 238
Espectrometría alfa
Suelos
Description
Summary:A method that combines the use of non-destructive neutron activation analysis and high-resolution spectrometry has been developed for determination of the activities of U-234 and U-238 in geological samples of low uranium content. The U-238 content is determined by k0-based neutron activation analysis, whereas the U-234/U-238 relationship is measured by spectrometry after isolation and electrodeposition of the uranium extracted from a lixiviation with 6 M HCl. The main advantage of the method is the simplicity of the chemical operations, including the fact that the steps destined to assure similar chemical state for the tracer and the uranium species present in the sample are not necessary. The method was applied to soil samples from sites of the north Peru coast. Uranium concentration range 3 to 40 mg/kg and the isotopic composition correspond to natural uranium, with about 10 % uncertainty.