Unusual nucleophilic versus electrophilic aromatic substitution on nitroanilines
The reaction of the regioisomeric nitroanilines with KI and HNOs/bentonite system using microwave energy in solvent-free conditions is reported. In accordance with the obtained results, an unusual competence between nucleophilic aromatic substitution versus electrophilic aromatic substitution was de...
| Autores: | , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2000 |
| País: | México |
| Institución: | Universidad Nacional Autónoma de México |
| Repositorio: | Sistema de Información de la Facultad de Ciencias, UNAM |
| OAI Identifier: | oai:repositorio.fciencias.unam.mx:11154/2012 |
| Acceso en línea: | http://hdl.handle.net/11154/2012 |
| Access Level: | acceso abierto |
| Palabra clave: | Chemistry, Physical nitroanilines bentonite nucleophilic electrophilic substitution |
| Sumario: | The reaction of the regioisomeric nitroanilines with KI and HNOs/bentonite system using microwave energy in solvent-free conditions is reported. In accordance with the obtained results, an unusual competence between nucleophilic aromatic substitution versus electrophilic aromatic substitution was detected. With the para isomer two products were obtained, one for each reaction type |
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