Influence of incorporating a small amount of silica on the catalytic performance of a MoO3/Al2O3 catalyst in ethanol oxidative dehydrogenation
The influence of incorporating a small amount of silica on the catalytic performance of MoO3/Al2O3 catalyst was studied. Molybdenum supported on pure alumina and 5% SiO2-Al2O3 supports were synthesized. The catalysts were characterized by XRD, Raman, UV-Vis and IR spectroscopies, FE-SEM microscopy,...
| Autores: | , , , , , |
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| Tipo de documento: | artigo |
| Estado: | Versão publicada |
| Data de publicação: | 2019 |
| País: | México |
| Recursos: | UNIVERSIDAD NACIONAL AUTÓNOMA DE MÉXICO |
| Repositório: | Journal of Applied Research and Technology |
| Idioma: | inglês |
| OAI Identifier: | oai:ojs2.localhost:article/746 |
| Acesso em linha: | https://jart.icat.unam.mx/index.php/jart/article/view/746 |
| Access Level: | Acceso aberto |
| Palavra-chave: | Molybdenum oxide catalysts alumina support dispersion of Mo oxide catalysts acetaldehyde production ethanol oxy-dehydrogenation |
| Resumo: | The influence of incorporating a small amount of silica on the catalytic performance of MoO3/Al2O3 catalyst was studied. Molybdenum supported on pure alumina and 5% SiO2-Al2O3 supports were synthesized. The catalysts were characterized by XRD, Raman, UV-Vis and IR spectroscopies, FE-SEM microscopy, and their activity was evaluated in the oxidative dehydrogenation of ethanol to acetaldehyde. Molybdenum supported on pure alumina gives a 74% yield to acetaldehyde (at 573 K) due to the generation of oxy-dehydrogenation active sites by molybdenum and to the decrement of the alumina dehydration sites. For the molybdenum catalyst supported on silica-containing alumina, the molybdenum species were displaced from the strongest alumina’s acid-base couples, located on nanoparticles edges, corners and defects, to weaker ones located on plane faces causing the rise of weakly bonded species with less active redox behavior. |
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