Development of Bilayer Biodegradable Composites Containing Cellulose Nanocrystals with Antioxidant Properties

The interest in the development of novel biodegradable composites has increased over last years, and multilayer composites allow the design of materials with functionality and improved properties. In this work, bilayer structures based on a coated zein layer containing quercetin and cellulose nanocr...

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Detalhes bibliográficos
Autores: Velásquez, Eliezer, Rojas, Adrián, Piña, Constanza, Galotto, María José, López de Dicastillo, Carol
Tipo de documento: artigo
Estado:Versão publicada
Data de publicação:2019
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositório:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/376897
Acesso em linha:http://hdl.handle.net/10261/376897
https://api.elsevier.com/content/abstract/scopus_id/85079174134
Access Level:Acceso aberto
Palavra-chave:Active packaging
Cellulose nanocrystals
Poly(acid lactic), bilayer
Quercetin
Zein
active packaging
Descrição
Resumo:The interest in the development of novel biodegradable composites has increased over last years, and multilayer composites allow the design of materials with functionality and improved properties. In this work, bilayer structures based on a coated zein layer containing quercetin and cellulose nanocrystals (CNC) over an extruded poly(lactic acid) (PLA) layer were developed and characterized. Bilayer composites were successfully obtained and presented a total thickness of approx. 90 µm. The coated zein layer and quercetin gave a yellowish tone to the composites. The incorporation of the zein layer containing CNC decreased the volatile release rate during thermal degradation. Regarding to mechanical properties, bilayer composites presented lower brittleness and greater ductility evidenced by a lower Young's modulus and higher elongation values. Water permeability values of bilayer composites greatly increased with humidity and the zein coated layer containing quercetin increased this effect. Experimental data of quercetin release kinetics from bilayer structures indicated a higher release for an alcoholic food system, and the incorporation of cellulose nanocrystals did not influence the quercetin diffusion process.