Determination of Polycyclic Aromatic Hydrocarbons and Organic Molecular Tracer Compounds in Dusts Samples from Schools in Puchuncaví and Quintero (Chile)
This article belongs to the Special Issue Emerging Contaminants and Their Transformation Products in the Environment: Advanced Analytical Methods for Assessing Ecological and Human Health Impacts.
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| Formato: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2026 |
| País: | España |
| Recursos: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/421530 |
| Acesso em linha: | http://hdl.handle.net/10261/421530 |
| Access Level: | acceso abierto |
| Palavra-chave: | Air pollution Organic molecular tracer compounds Polycyclic aromatic hydrocarbons Primary school |
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Determination of Polycyclic Aromatic Hydrocarbons and Organic Molecular Tracer Compounds in Dusts Samples from Schools in Puchuncaví and Quintero (Chile)Parra, SonniaBravo, Manuel A.Van Drooge, Barend L.Air pollutionOrganic molecular tracer compoundsPolycyclic aromatic hydrocarbonsPrimary schoolThis article belongs to the Special Issue Emerging Contaminants and Their Transformation Products in the Environment: Advanced Analytical Methods for Assessing Ecological and Human Health Impacts.This investigation was conducted in order to gain a first knowledge of concentrations, distribution patterns, and potential sources of 16 US EPA priority polycyclic aromatic hydrocarbons (PAHs) and organic molecular tracer compounds in deposition dust samples collected in the Valparaiso region, Chile. Dust was sampled in schools (indoor and outdoor) that are located in Puchuncaví and Quintero. Source apportionment analysis using the concentrations of PAHs; glucose, mannitol, sucrose, fructose; di-2-ethylhexyl phthalate; hopanes, and levoglucosan as molecular tracer compounds showed three sources of contribution. The first (46.38%) was related to incomplete combustion processes (Acy, Flu, Ant, Flt, Pyr, and BaA), a second source (20%) represented soil+ biomass burning (levoglucosan, α glucose, β glucose, mannitol, sucrose, and fructose), and a third source (10.26%) was dominated only by 27_norhopane, 27_hopane, which are related to traffic. To assess potential health risks for schoolchildren, the study calculated the benzo[a]pyrene equivalent (BaPE) toxicity and the incremental lifetime cancer risk (ILCR). Toxicity equivalent (TEQ) results showed that the main contributor to overall toxicity in PAHs, especially in schools located in Puchuncaví, was benzo[a]pyrene (BaP), followed by benzo[α]anthracene (BaA), benzo[b]fluoranthene (BbF), benzo[k]fluoranthene (BkF), indeno[1,2,3-cd] pyrene (IcdP), and dibenzo[a,h]anthracene (DahA). According to the calculated ILCR values, the highest cancer risk was associated with dust ingestion (both indoor and outdoor) for ∑16PAHs, ranging from 1.14 × 10−3 to 8.88 × 10−4. This was followed by dermal contact (1.27 × 10−5 to 7.27 × 10−7) and inhalation (1.22 × 10−8 to 9.99 × 10−9).The research work of Sonnia Parra was partially supported by to the Dirección de Investigación y Estudios Avanzados (VRIEA-PUCV) project 039.345/2021. Barend Drooge was supported by the European Commission EU Horizon for financial support (IN CHILD HEALTH EU Horizon 101056883).Peer reviewedMultidisciplinary Digital Publishing InstitutePontificia Universidad Católica de ValparaísoEuropean CommissionBravo, Manuel A. [0000-0002-4548-6265]Van Drooge, Barend L. [0000-0002-6434-3390]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2026202620262026info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://hdl.handle.net/10261/421530reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/EC/HE/101056883The underlying dataset has been published as supplementary material of the article in the publisher platform at DOI https://doi.org/10.3390/molecules31050818https://doi.org/10.3390/molecules31050818Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/4215302026-05-22T06:33:51Z |
| dc.title.none.fl_str_mv |
Determination of Polycyclic Aromatic Hydrocarbons and Organic Molecular Tracer Compounds in Dusts Samples from Schools in Puchuncaví and Quintero (Chile) |
| title |
Determination of Polycyclic Aromatic Hydrocarbons and Organic Molecular Tracer Compounds in Dusts Samples from Schools in Puchuncaví and Quintero (Chile) |
| spellingShingle |
Determination of Polycyclic Aromatic Hydrocarbons and Organic Molecular Tracer Compounds in Dusts Samples from Schools in Puchuncaví and Quintero (Chile) Parra, Sonnia Air pollution Organic molecular tracer compounds Polycyclic aromatic hydrocarbons Primary school |
| title_short |
Determination of Polycyclic Aromatic Hydrocarbons and Organic Molecular Tracer Compounds in Dusts Samples from Schools in Puchuncaví and Quintero (Chile) |
| title_full |
Determination of Polycyclic Aromatic Hydrocarbons and Organic Molecular Tracer Compounds in Dusts Samples from Schools in Puchuncaví and Quintero (Chile) |
| title_fullStr |
Determination of Polycyclic Aromatic Hydrocarbons and Organic Molecular Tracer Compounds in Dusts Samples from Schools in Puchuncaví and Quintero (Chile) |
| title_full_unstemmed |
Determination of Polycyclic Aromatic Hydrocarbons and Organic Molecular Tracer Compounds in Dusts Samples from Schools in Puchuncaví and Quintero (Chile) |
| title_sort |
Determination of Polycyclic Aromatic Hydrocarbons and Organic Molecular Tracer Compounds in Dusts Samples from Schools in Puchuncaví and Quintero (Chile) |
| dc.creator.none.fl_str_mv |
Parra, Sonnia Bravo, Manuel A. Van Drooge, Barend L. |
| author |
Parra, Sonnia |
| author_facet |
Parra, Sonnia Bravo, Manuel A. Van Drooge, Barend L. |
| author_role |
author |
| author2 |
Bravo, Manuel A. Van Drooge, Barend L. |
| author2_role |
author author |
| dc.contributor.none.fl_str_mv |
Pontificia Universidad Católica de Valparaíso European Commission Bravo, Manuel A. [0000-0002-4548-6265] Van Drooge, Barend L. [0000-0002-6434-3390] Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72] |
| dc.subject.none.fl_str_mv |
Air pollution Organic molecular tracer compounds Polycyclic aromatic hydrocarbons Primary school |
| topic |
Air pollution Organic molecular tracer compounds Polycyclic aromatic hydrocarbons Primary school |
| description |
This article belongs to the Special Issue Emerging Contaminants and Their Transformation Products in the Environment: Advanced Analytical Methods for Assessing Ecological and Human Health Impacts. |
| publishDate |
2026 |
| dc.date.none.fl_str_mv |
2026 2026 2026 2026 |
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info:eu-repo/semantics/article http://purl.org/coar/resource_type/c_6501 Publisher's version info:eu-repo/semantics/publishedVersion |
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article |
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publishedVersion |
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http://hdl.handle.net/10261/421530 |
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http://hdl.handle.net/10261/421530 |
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Inglés |
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Inglés |
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#PLACEHOLDER_PARENT_METADATA_VALUE# info:eu-repo/grantAgreement/EC/HE/101056883 The underlying dataset has been published as supplementary material of the article in the publisher platform at DOI https://doi.org/10.3390/molecules31050818 https://doi.org/10.3390/molecules31050818 Sí |
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info:eu-repo/semantics/openAccess |
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openAccess |
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application/pdf |
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Multidisciplinary Digital Publishing Institute |
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Multidisciplinary Digital Publishing Institute |
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reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC instname:Consejo Superior de Investigaciones Científicas (CSIC) |
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Consejo Superior de Investigaciones Científicas (CSIC) |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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