Preparation and characterization of electrospun pectin-based films and their application in sustainable aroma barrier multilayer packaging

Pectin was first dissolved in distilled water and blended with low contents of polyethylene oxide 2000 (PEO2000) as the carrier polymer to produce electrospun fibers. The electrospinning of the water solution of pectin at 9.5 wt% containing 0.5 wt% PEO2000 was selected as it successfully resulted in...

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Autores: Akinalan Balik, Busra, Argin, Sanem, Lagarón Cabello, José María, Torres Giner, Sergio
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2019
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/196268
Acceso en línea:http://hdl.handle.net/10261/196268
Access Level:acceso abierto
Palabra clave:Pectin
Electrospinning
Annealing
Barrier interlayers
Food packaging
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spelling Preparation and characterization of electrospun pectin-based films and their application in sustainable aroma barrier multilayer packagingAkinalan Balik, BusraArgin, SanemLagarón Cabello, José MaríaTorres Giner, SergioPectinElectrospinningAnnealingBarrier interlayersFood packagingPectin was first dissolved in distilled water and blended with low contents of polyethylene oxide 2000 (PEO2000) as the carrier polymer to produce electrospun fibers. The electrospinning of the water solution of pectin at 9.5 wt% containing 0.5 wt% PEO2000 was selected as it successfully resulted in continuous and non-defected ultrathin fibers with the highest pectin content. However, annealing of the resultant pectin-based fibers, tested at different conditions, developed films with low mechanical integrity, high porosity, and also dark color due to their poor thermal stability. Then, to improve the film-forming process of the electrospun mats, two plasticizers, namely glycerol and polyethylene glycol 900 (PEG900), were added to the selected pectin solution in the 2–3 wt% range. The optimal annealing conditions were found at 150 °C with a pressure of 12 kN load for 1 min when applied to the electrospun pectin mats containing 5 wt% PEO2000 and 30 wt% glycerol and washed previously with dichloromethane. This process led to completely homogenous films with low porosity and high transparency due to a phenomenon of fibers coalescence. Finally, the selected electrospun pectin-based film was applied as an interlayer between two external layers of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) by the electrospinning coating technology and the whole structure was annealed to produce a fully bio-based and biodegradable multilayer film with enhanced barrier performance to water vapor and limonene.This study was supported by the Turkish Scientific and Technological Research Council (TUBITAK) 2214-A International Research Fellowship Programme for PhD Students and by the Spanish Ministry of Science, Innovation, and Universities (MICIU) project numbers AGL2015-63855-C2-1-R. S.T.-G. is a recipient of a Juan de la Cierva—Incorporación contract (IJCI-2016-29675) from MICIU.Peer reviewedMultidisciplinary Digital Publishing InstituteThe Scientific and Technological Research Council of TürkiyeMinisterio de Economía y Competitividad (España)Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2019201920192019info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/196268reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Español#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/AGL2015-63855-C2-1-Rinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/IJCI-2016-29675https://doi.org/10.3390/app9235136Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/1962682026-05-22T06:33:51Z
dc.title.none.fl_str_mv Preparation and characterization of electrospun pectin-based films and their application in sustainable aroma barrier multilayer packaging
title Preparation and characterization of electrospun pectin-based films and their application in sustainable aroma barrier multilayer packaging
spellingShingle Preparation and characterization of electrospun pectin-based films and their application in sustainable aroma barrier multilayer packaging
Akinalan Balik, Busra
Pectin
Electrospinning
Annealing
Barrier interlayers
Food packaging
title_short Preparation and characterization of electrospun pectin-based films and their application in sustainable aroma barrier multilayer packaging
title_full Preparation and characterization of electrospun pectin-based films and their application in sustainable aroma barrier multilayer packaging
title_fullStr Preparation and characterization of electrospun pectin-based films and their application in sustainable aroma barrier multilayer packaging
title_full_unstemmed Preparation and characterization of electrospun pectin-based films and their application in sustainable aroma barrier multilayer packaging
title_sort Preparation and characterization of electrospun pectin-based films and their application in sustainable aroma barrier multilayer packaging
dc.creator.none.fl_str_mv Akinalan Balik, Busra
Argin, Sanem
Lagarón Cabello, José María
Torres Giner, Sergio
author Akinalan Balik, Busra
author_facet Akinalan Balik, Busra
Argin, Sanem
Lagarón Cabello, José María
Torres Giner, Sergio
author_role author
author2 Argin, Sanem
Lagarón Cabello, José María
Torres Giner, Sergio
author2_role author
author
author
dc.contributor.none.fl_str_mv The Scientific and Technological Research Council of Türkiye
Ministerio de Economía y Competitividad (España)
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Pectin
Electrospinning
Annealing
Barrier interlayers
Food packaging
topic Pectin
Electrospinning
Annealing
Barrier interlayers
Food packaging
description Pectin was first dissolved in distilled water and blended with low contents of polyethylene oxide 2000 (PEO2000) as the carrier polymer to produce electrospun fibers. The electrospinning of the water solution of pectin at 9.5 wt% containing 0.5 wt% PEO2000 was selected as it successfully resulted in continuous and non-defected ultrathin fibers with the highest pectin content. However, annealing of the resultant pectin-based fibers, tested at different conditions, developed films with low mechanical integrity, high porosity, and also dark color due to their poor thermal stability. Then, to improve the film-forming process of the electrospun mats, two plasticizers, namely glycerol and polyethylene glycol 900 (PEG900), were added to the selected pectin solution in the 2–3 wt% range. The optimal annealing conditions were found at 150 °C with a pressure of 12 kN load for 1 min when applied to the electrospun pectin mats containing 5 wt% PEO2000 and 30 wt% glycerol and washed previously with dichloromethane. This process led to completely homogenous films with low porosity and high transparency due to a phenomenon of fibers coalescence. Finally, the selected electrospun pectin-based film was applied as an interlayer between two external layers of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) by the electrospinning coating technology and the whole structure was annealed to produce a fully bio-based and biodegradable multilayer film with enhanced barrier performance to water vapor and limonene.
publishDate 2019
dc.date.none.fl_str_mv 2019
2019
2019
2019
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/196268
url http://hdl.handle.net/10261/196268
dc.language.none.fl_str_mv Español
language_invalid_str_mv Español
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/AGL2015-63855-C2-1-R
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/IJCI-2016-29675
https://doi.org/10.3390/app9235136
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.228081

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