Metal complexes with naphthalene-diimide and perylene-diimide-based ligands: supramolecular interactions and catalytic implications

Compendi d'articles

Detalhes bibliográficos
Autor: Gutiérrez Peña, Cristian Leonardo
Formato: tesis doctoral
Estado:Versión publicada
Fecha de publicación:2025
País:España
Recursos:CBUC, CESCA
Repositorio:TDR. Tesis Doctorales en Red
OAI Identifier:oai:www.tdx.cat:10803/693627
Acesso em linha:http://hdl.handle.net/10803/693627
Access Level:acceso abierto
Palavra-chave:Organometallics
Homogeneous catalysis
N-Heterocyclic carbenes
Supramolecular
Ciències
54
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spelling Metal complexes with naphthalene-diimide and perylene-diimide-based ligands: supramolecular interactions and catalytic implicationsGutiérrez Peña, Cristian LeonardoOrganometallicsHomogeneous catalysisN-Heterocyclic carbenesSupramolecularCiències54Compendi d'articlesThis doctoral thesis delves into the design and development of new ligand precursors and organometallic complexes through the combination of two different types of rylene-diimides (RDIs), with N-heterocyclic carbene (NHC)-based ligands. The novelty and interest of the results described in this doctoral thesis can be summarized in the following three points: • We show that imide functionalization of PDI/NDIs with NHC units can be used as a way to generate redox-switchable ligands with application in homogeneous catalysis. • We describe how the catalytic properties of a simple metal complex can be reversibly modified by using tailored-designed redox-switchable rylene-decorated NHC ligands, thus offering a new and simple approach to modulate the catalytic activity and to elucidate or review reaction mechanisms. • We describe and fully characterize a new type of (chloride)lp– π interaction between the chloride ligands of the Ir(III) complex and the heterocycles of the NDI/PDI moieties combining spectroscopic/computational determination of the lp–π interaction.Programa de Doctorat en CiènciesUniversitat Jaume IPeris, EduardoPoyatos, MacarenaPeris, EduardoUniversitat Jaume I. Escola de Doctorat202520252025info:eu-repo/semantics/doctoralThesisinfo:eu-repo/semantics/publishedVersion274 p.application/pdfhttp://hdl.handle.net/10803/693627TDX (Tesis Doctorals en Xarxa)reponame:TDR. Tesis Doctorales en Redinstname:CBUC, CESCAInglésL'accés als continguts d'aquesta tesi queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons: http://creativecommons.org/licenses/by-sa/4.0/http://creativecommons.org/licenses/by-sa/4.0/info:eu-repo/semantics/openAccessoai:www.tdx.cat:10803/6936272026-06-14T12:46:07Z
dc.title.none.fl_str_mv Metal complexes with naphthalene-diimide and perylene-diimide-based ligands: supramolecular interactions and catalytic implications
title Metal complexes with naphthalene-diimide and perylene-diimide-based ligands: supramolecular interactions and catalytic implications
spellingShingle Metal complexes with naphthalene-diimide and perylene-diimide-based ligands: supramolecular interactions and catalytic implications
Gutiérrez Peña, Cristian Leonardo
Organometallics
Homogeneous catalysis
N-Heterocyclic carbenes
Supramolecular
Ciències
54
title_short Metal complexes with naphthalene-diimide and perylene-diimide-based ligands: supramolecular interactions and catalytic implications
title_full Metal complexes with naphthalene-diimide and perylene-diimide-based ligands: supramolecular interactions and catalytic implications
title_fullStr Metal complexes with naphthalene-diimide and perylene-diimide-based ligands: supramolecular interactions and catalytic implications
title_full_unstemmed Metal complexes with naphthalene-diimide and perylene-diimide-based ligands: supramolecular interactions and catalytic implications
title_sort Metal complexes with naphthalene-diimide and perylene-diimide-based ligands: supramolecular interactions and catalytic implications
dc.creator.none.fl_str_mv Gutiérrez Peña, Cristian Leonardo
author Gutiérrez Peña, Cristian Leonardo
author_facet Gutiérrez Peña, Cristian Leonardo
author_role author
dc.contributor.none.fl_str_mv Peris, Eduardo
Poyatos, Macarena
Peris, Eduardo
Universitat Jaume I. Escola de Doctorat
dc.subject.none.fl_str_mv Organometallics
Homogeneous catalysis
N-Heterocyclic carbenes
Supramolecular
Ciències
54
topic Organometallics
Homogeneous catalysis
N-Heterocyclic carbenes
Supramolecular
Ciències
54
description Compendi d'articles
publishDate 2025
dc.date.none.fl_str_mv 2025
2025
2025
dc.type.none.fl_str_mv info:eu-repo/semantics/doctoralThesis
info:eu-repo/semantics/publishedVersion
format doctoralThesis
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10803/693627
url http://hdl.handle.net/10803/693627
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.rights.none.fl_str_mv http://creativecommons.org/licenses/by-sa/4.0/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-sa/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 274 p.
application/pdf
dc.publisher.none.fl_str_mv Universitat Jaume I
publisher.none.fl_str_mv Universitat Jaume I
dc.source.none.fl_str_mv TDX (Tesis Doctorals en Xarxa)
reponame:TDR. Tesis Doctorales en Red
instname:CBUC, CESCA
instname_str CBUC, CESCA
reponame_str TDR. Tesis Doctorales en Red
collection TDR. Tesis Doctorales en Red
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869420142708916224
score 15.812455

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