Exploring Reaction Conditions to Improve the Magnetic Response of Cobalt-Doped Ferrite Nanoparticles
With the aim of studying the influence of synthesis parameters in structural and magnetic properties of cobalt-doped magnetite nanoparticles, Fe3-xCoxO4 (0 < x < 0.15) samples were synthetized by thermal decomposition method at different reaction times (30-120 min). The Co ferrite nanoparticle...
| Autores: | , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2018 |
| País: | España |
| Institución: | Universidad del País Vasco |
| Repositorio: | Addi. Archivo Digital para la Docencia y la Investigación |
| OAI Identifier: | oai:addi.ehu.eus:10810/29600 |
| Acceso en línea: | http://hdl.handle.net/10810/29600 |
| Access Level: | acceso abierto |
| Palabra clave: | co-doped ferrite magnetic nanoparticles superparamagnetism anisotropy energy magnetic properties thermal-decomposition Cofe2o4 nanoparticles MFe2O4 M CO anisotropy nanocrystals size NI surfactant morphology |
| Sumario: | With the aim of studying the influence of synthesis parameters in structural and magnetic properties of cobalt-doped magnetite nanoparticles, Fe3-xCoxO4 (0 < x < 0.15) samples were synthetized by thermal decomposition method at different reaction times (30-120 min). The Co ferrite nanoparticles are monodisperse with diameters between 6 and 11 nm and morphologies depending on reaction times, varying from spheric, cuboctahedral, to cubic. Chemical analysis and X-ray diffraction were used to confirm the composition, high crystallinity, and pure-phase structure. The investigation of the magnetic properties, both magnetization and electronic magnetic resonance, has led the conditions to improve the magnetic response of doped nanoparticles. Magnetization values of 86 emu center dot g(-1) at room temperature (R.T.) have been obtained for the sample with the highest Co content and the highest reflux time. Magnetic characterization also displays a dependence of the magnetic anisotropy constant with the varying cobalt content. |
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