Production of Bioadsorbents via Low-Temperature Pyrolysis of Exhausted Olive Pomace for the Removal of Methylene Blue from Aqueous Media
In this work, biochars were produced by pyrolysis of exhausted olive pomace and evaluated as low-cost adsorbents for the removal of methylene blue (MB) from aqueous solutions. The biochar obtained at 400 °C for 1 h, which exhibited the best adsorption performance, was characterized by FTIR, N2 adsor...
| Autores: | , , , |
|---|---|
| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2025 |
| País: | España |
| Institución: | Universidad de Jaén |
| Repositorio: | RUJA. Repositorio Institucional de la Producción Científica de la Universidad de Jaén |
| OAI Identifier: | oai:ruja.ujaen.es:10953/7240 |
| Acceso en línea: | https://hdl.handle.net/10953/7240 |
| Access Level: | acceso abierto |
| Palabra clave: | exhausted olive pomace biochar adsorption kinetics isotherms methylene blue water treatment 2.90.27 |
| Sumario: | In this work, biochars were produced by pyrolysis of exhausted olive pomace and evaluated as low-cost adsorbents for the removal of methylene blue (MB) from aqueous solutions. The biochar obtained at 400 °C for 1 h, which exhibited the best adsorption performance, was characterized by FTIR, N2 adsorption–desorption isotherms, SEM-EDX, and proximate analysis, revealing a mesoporous structure with a relatively low specific surface area but enriched in surface functional groups, likely due to the partial degradation of lignocellulosic components. Adsorption experiments were conducted to optimize operational parameters such as solid particle size (2–3 mm), agitation speed (75 rpm), and bioadsorbent dosage (1 g per 0.05 L of MB solution), which allowed for dye removal efficiencies close to 100%. Kinetic studies showed that MB adsorption followed a pseudosecond- order model, while equilibrium data at 30 °C were best described by the Langmuir isotherm (R2 = 0.999; SE = 4.25%), suggesting monolayer coverage and strong adsorbate– adsorbent affinity. Desorption trials using water, ethanol, and their mixtures resulted in low MB recovery, whereas the addition of 10% acetic acid significantly improved desorption performance. Under optimal conditions, up to 52% of the retained dye was recovered. |
|---|