Engineering molecular aggregate spectra

We show that optical properties of linear molecular aggregates undergo drastic changes when aggregates are deposited on a metal surface. The dipole-dipole interactions of monomers with their images can result in strong re-structuring of both the exciton band and the absorption spectrum, depending on...

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Detalhes bibliográficos
Autor: Malyshev, Andrey
Tipo de documento: artigo
Data de publicação:2009
País:España
Recursos:Universidad Complutense de Madrid (UCM)
Repositório:Docta Complutense
Idioma:inglês
OAI Identifier:oai:docta.ucm.es:20.500.14352/42784
Acesso em linha:https://hdl.handle.net/20.500.14352/42784
Access Level:Acceso aberto
Palavra-chave:538.9
Absorption-spectra
Gold nanoparticles
Optical-spectra
Superradiant
Física de materiales
Física del estado sólido
2211 Física del Estado Sólido
Descrição
Resumo:We show that optical properties of linear molecular aggregates undergo drastic changes when aggregates are deposited on a metal surface. The dipole-dipole interactions of monomers with their images can result in strong re-structuring of both the exciton band and the absorption spectrum, depending on the arrangement of the monomer transition dipoles with respect to the surface.