Direct observation of the chemical transformations in BiVO4 photoanodes upon prolonged light-aging treatments
Exposing BiVO photoanodes to light-aging treatments is known to produce a significant photocurrent enhancement. Until now, the interpretation given to this phenomenon is associated to the formation of oxygen vacancies and little is reported about chemical changes in the material. Herein, the chemica...
| Authors: | , , , , , , , , |
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| Format: | article |
| Publication Date: | 2022 |
| Country: | España |
| Institution: | Universitat Autònoma de Barcelona |
| Repository: | Dipòsit Digital de Documents de la UAB |
| Language: | English |
| OAI Identifier: | oai:ddd.uab.cat:266327 |
| Online Access: | https://ddd.uab.cat/record/266327 https://dx.doi.org/urn:doi:10.1002/solr.202200132 |
| Access Level: | Open access |
| Keyword: | Bi segregation BiVO4 Light-aging treatments Oxygen vacancies |
| Summary: | Exposing BiVO photoanodes to light-aging treatments is known to produce a significant photocurrent enhancement. Until now, the interpretation given to this phenomenon is associated to the formation of oxygen vacancies and little is reported about chemical changes in the material. Herein, the chemical segregation of Bi species toward the surface upon light-aging treatment is demonstrated, which takes place with the concomitant formation of intra-bandgap states associated to the oxygen vacancies. It is further demonstrated that these intra-bandgap states are photoactive and generate photocurrent under infrared excitation. These results highlight the importance of understanding light-induced effects while employing multinary metal oxide photoelectrodes. |
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