Effectiveness of different immobilized Candida antarctica lipase b (iCaLB) in the production of biobased oligoester derivatives from poly(butylene succinate) (PBS) and poly(butylene adipate) (PBA)

10 p.

Detalhes bibliográficos
Autores: Sena, Belén, Aceña Bonilla, José Luis|||0000-0002-1777-8199, Novella Robisco, José Luis|||0009-0009-8169-4182, Monje Martínez, Belén, Martí Montaner, Laura, Fernández Bachiller, María Isabel
Formato: artículo
Fecha de publicación:2023
País:España
Recursos:Universidad de Alcalá (UAH)
Repositorio:e_Buah Biblioteca Digital Universidad de Alcalá
Idioma:inglés
OAI Identifier:oai:ebuah.uah.es:10017/67906
Acesso em linha:http://hdl.handle.net/10017/67906
https://dx.doi.org/10.1016/j.eurpolymj.2023.112575
Access Level:acceso abierto
Palavra-chave:Poly(butylene succinate)
Poly(butylene adipate)
Enzymatic polymerization
Biobased polyesters
Biodegradable polymers
Química
Ciencia de los materiales
Chemistry
Materials science
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network_acronym_str ES
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repository_id_str
spelling Effectiveness of different immobilized Candida antarctica lipase b (iCaLB) in the production of biobased oligoester derivatives from poly(butylene succinate) (PBS) and poly(butylene adipate) (PBA)Sena, BelénAceña Bonilla, José Luis|||0000-0002-1777-8199Novella Robisco, José Luis|||0009-0009-8169-4182Monje Martínez, BelénMartí Montaner, LauraFernández Bachiller, María IsabelPoly(butylene succinate)Poly(butylene adipate)Enzymatic polymerizationBiobased polyestersBiodegradable polymersQuímicaCiencia de los materialesChemistryMaterials science10 p.The use of lipases (Candida antarctica Lipase B, CaLB) immobilized on different solid supports for the preparation of biodegradable aliphatic polyesters poly(butylene adipate) (PBA) and poly(butylene succinate) (PBS) by esterification of unactivated dicarboxylic acids with 1,4-butanediol is presented. The immobilization of CaLB through absorption or a covalent attachment to different solid supports enhances their use as a catalyst for polycondensation reactions both in solution and in bulk. The results indicated that the different immobilized CaLBs were able to catalyze succesfully the polycondensation of both succinic and adipic acid with 1,4-butanediol, yielding the linear aliphatic polyesters PBS and PBA, respectively, by using a two-step polymerization process. Techniques such as nuclear magnetic resonance (NMR), relative molar mass obtained by gel permeation chromatography (GPC) and differential scanning calorimetry (DSC) were applied to compare the influence of the solid support on the obtention of PBA and PBS. Herein, it is shown that the nature of the solid support employed on each immobilized CaLB enzyme modifies the activity and effectivity towards polycondensation of PBA and PBS having a strong influence on the molecular weights and crystallinity.Instituto Valenciano de Competitividad Empresarial20232023-11-07journal articlehttp://purl.org/coar/resource_type/c_6501NAhttp://purl.org/coar/version/c_be7fb7dd8ff6fe43info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10017/67906https://dx.doi.org/10.1016/j.eurpolymj.2023.112575reponame:e_Buah Biblioteca Digital Universidad de Alcaláinstname:Universidad de Alcalá (UAH)InglésengIVACE IMDEEA%2F2019%2F84 ESIVACE Not available IMDEEA%2F2020%2F54open accesshttp://purl.org/coar/access_right/c_abf2Attribution 4.0 Internationalhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:ebuah.uah.es:10017/679062026-06-18T11:13:07Z
dc.title.none.fl_str_mv Effectiveness of different immobilized Candida antarctica lipase b (iCaLB) in the production of biobased oligoester derivatives from poly(butylene succinate) (PBS) and poly(butylene adipate) (PBA)
title Effectiveness of different immobilized Candida antarctica lipase b (iCaLB) in the production of biobased oligoester derivatives from poly(butylene succinate) (PBS) and poly(butylene adipate) (PBA)
spellingShingle Effectiveness of different immobilized Candida antarctica lipase b (iCaLB) in the production of biobased oligoester derivatives from poly(butylene succinate) (PBS) and poly(butylene adipate) (PBA)
Sena, Belén
Poly(butylene succinate)
Poly(butylene adipate)
Enzymatic polymerization
Biobased polyesters
Biodegradable polymers
Química
Ciencia de los materiales
Chemistry
Materials science
title_short Effectiveness of different immobilized Candida antarctica lipase b (iCaLB) in the production of biobased oligoester derivatives from poly(butylene succinate) (PBS) and poly(butylene adipate) (PBA)
title_full Effectiveness of different immobilized Candida antarctica lipase b (iCaLB) in the production of biobased oligoester derivatives from poly(butylene succinate) (PBS) and poly(butylene adipate) (PBA)
title_fullStr Effectiveness of different immobilized Candida antarctica lipase b (iCaLB) in the production of biobased oligoester derivatives from poly(butylene succinate) (PBS) and poly(butylene adipate) (PBA)
title_full_unstemmed Effectiveness of different immobilized Candida antarctica lipase b (iCaLB) in the production of biobased oligoester derivatives from poly(butylene succinate) (PBS) and poly(butylene adipate) (PBA)
title_sort Effectiveness of different immobilized Candida antarctica lipase b (iCaLB) in the production of biobased oligoester derivatives from poly(butylene succinate) (PBS) and poly(butylene adipate) (PBA)
dc.creator.none.fl_str_mv Sena, Belén
Aceña Bonilla, José Luis|||0000-0002-1777-8199
Novella Robisco, José Luis|||0009-0009-8169-4182
Monje Martínez, Belén
Martí Montaner, Laura
Fernández Bachiller, María Isabel
author Sena, Belén
author_facet Sena, Belén
Aceña Bonilla, José Luis|||0000-0002-1777-8199
Novella Robisco, José Luis|||0009-0009-8169-4182
Monje Martínez, Belén
Martí Montaner, Laura
Fernández Bachiller, María Isabel
author_role author
author2 Aceña Bonilla, José Luis|||0000-0002-1777-8199
Novella Robisco, José Luis|||0009-0009-8169-4182
Monje Martínez, Belén
Martí Montaner, Laura
Fernández Bachiller, María Isabel
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Poly(butylene succinate)
Poly(butylene adipate)
Enzymatic polymerization
Biobased polyesters
Biodegradable polymers
Química
Ciencia de los materiales
Chemistry
Materials science
topic Poly(butylene succinate)
Poly(butylene adipate)
Enzymatic polymerization
Biobased polyesters
Biodegradable polymers
Química
Ciencia de los materiales
Chemistry
Materials science
description 10 p.
publishDate 2023
dc.date.none.fl_str_mv 2023
2023-11-07
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
NA
http://purl.org/coar/version/c_be7fb7dd8ff6fe43
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10017/67906
https://dx.doi.org/10.1016/j.eurpolymj.2023.112575
url http://hdl.handle.net/10017/67906
https://dx.doi.org/10.1016/j.eurpolymj.2023.112575
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv IVACE IMDEEA%2F2019%2F84 ES
IVACE Not available IMDEEA%2F2020%2F54
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution 4.0 International
http://creativecommons.org/licenses/by/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution 4.0 International
http://creativecommons.org/licenses/by/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:e_Buah Biblioteca Digital Universidad de Alcalá
instname:Universidad de Alcalá (UAH)
instname_str Universidad de Alcalá (UAH)
reponame_str e_Buah Biblioteca Digital Universidad de Alcalá
collection e_Buah Biblioteca Digital Universidad de Alcalá
repository.name.fl_str_mv
repository.mail.fl_str_mv
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