The microbiological transformation of some ent-3B-hydroxykaur-16-enes by Gibberella fujikuroi

The preparation of ent-3B-hydroxykaur-16-ene from linearol and of ent-3B,18-dihydroxykaur-16-ene from foliol is decribed. The microbiological transformation of these and of foliol by Gibberella fujikuroi has been studied. A 3a-hydroxyl group appears to exert an inhibitory effect on transformations i...

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Detalhes bibliográficos
Autores: Fraga, Braulio M., González, Antonio G., Hanson, James R., Hernández, Melchor G.
Formato: artículo
Fecha de publicación:1981
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/21993
Acesso em linha:http://hdl.handle.net/10261/21993
Access Level:acceso abierto
Palavra-chave:Gibberella fujikuroi
tetracyclic diterpenoids
linearol
foliol
Descrição
Resumo:The preparation of ent-3B-hydroxykaur-16-ene from linearol and of ent-3B,18-dihydroxykaur-16-ene from foliol is decribed. The microbiological transformation of these and of foliol by Gibberella fujikuroi has been studied. A 3a-hydroxyl group appears to exert an inhibitory effect on transformations involving oxidation at C-19.