Structure, Composition, Transport Properties, and Electrochemical Performance of the Electrode-Electrolyte Interphase in Non-Aqueous Na-Ion Batteries

[EN] Rechargeable Li-ion battery technology has progressed due to the development of a suitable combination of electroactive materials, binders, electrolytes, additives, and electrochemical cycling protocols that resulted in the formation of a stable electrode-electrolyte interphase. It is expected...

ver descrição completa

Detalhes bibliográficos
Autores: Muñoz Márquez, Miguel Angel, Zarrabeitia Ipiña, Maider, Passerini, Stefano, Rojo Aparicio, Teófilo
Tipo de documento: artigo
Data de publicação:2022
País:España
Recursos:Universidad del País Vasco
Repositório:Addi. Archivo Digital para la Docencia y la Investigación
OAI Identifier:oai:addi.ehu.eus:10810/56018
Acesso em linha:http://hdl.handle.net/10810/56018
Access Level:Acceso aberto
Palavra-chave:advanced electrolytes
interface models
liquid electrolytes
Na-ion batteries
solid electrolyte interphase
transport properties
X-ray photoelectron spectroscopy
Descrição
Resumo:[EN] Rechargeable Li-ion battery technology has progressed due to the development of a suitable combination of electroactive materials, binders, electrolytes, additives, and electrochemical cycling protocols that resulted in the formation of a stable electrode-electrolyte interphase. It is expected that Na-ion technology will attain a position comparable to Li-ion batteries dependent on advancements in establishing a stable electrode-electrolyte interphase. However, Li and Na are both alkali metals with similar characteristics, yet the physicochemical properties of these systems differ. For this reason, a detailed study on the electrode-electrolyte interphase properties, composition, and structure is required to understand the factors that influence the battery's behavior. Herein, the research that has been performed on the electrode-electrolyte interphase for both anode and cathode in the most important families of electrode materials, including carbonate ester-based and advanced electrolytes such as ether-based carbonates and ionic liquids is presented.