Revealing dynamic behavior in high dielectric poly(thiourethane)-based vitrimer-like materials
Here, we have explored covalent adaptable networks (CANs) comprising poly(thiourethane)-based systems (PTUs). The PTUs were synthesized through the combination of thiol and isocyanate monomers in stoichiometric proportions, in the presence of dibutyltin dilaurate (DBTDL) as catalyst. Dynamic mechani...
| Autores: | , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2024 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/365385 |
| Acceso en línea: | http://hdl.handle.net/10261/365385 |
| Access Level: | acceso abierto |
| Palabra clave: | Covalent adaptable networks Vitrimer-like Poly(thiourethane) Glass transition temperature Topology freezing transition temperature Dielectric spectroscopy |
| Sumario: | Here, we have explored covalent adaptable networks (CANs) comprising poly(thiourethane)-based systems (PTUs). The PTUs were synthesized through the combination of thiol and isocyanate monomers in stoichiometric proportions, in the presence of dibutyltin dilaurate (DBTDL) as catalyst. Dynamic mechanical analysis (DMA) provided detailed insight into the vitrimeric behavior. Through these investigations, we evaluated the viscoelastic, thermomechanical, and vitrimeric properties. Additionally, broadband dielectric spectroscopy (BDS) revealed the various relaxation processes inherent in such vitrimer-like materials. We methodically examined the evolution of each relaxation in every prepared sample to comprehend the operational mechanisms in these vitrimer-like systems. Our findings underscore that depending on the PTU formulation, the glass transition temperature (Tg) and the topology freezing transition temperature (Tv) can be effectively distinguished and studied. Considering the high dipole moment of the dynamic bonds present in these systems, there is potential for utilizing them as dielectric materials working under the concept of dipolar glass polymers. Furthermore, the reversibility exhibited by their inner chemical structures positions them as promising candidates for active layers in capacitor devices, particularly for energy-related applications, with the ability to be recyclable while maintaining almost invariant both their mechanical and dielectric properties, thus promoting the extension of the lifespan of electronic devices. |
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