Crystal structure of (1Z,4Z)-2,4-dimethyl-3H-benzo[b][1,4]diazepine

The title compound, C11H12N2, is not planar due to the folding of the seven-membered ring. In the crystal, molecules are packed opposite each other to minimize the electronic repulsion but the long intermolecular distances indicate that no directional contacts are found.

Detalhes bibliográficos
Autores: Nieto, Carla I., Claramunt, Rosa M., Torralba, M. Carmen, Torres, M. Rosario, Elguero, José
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2017
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/151628
Acesso em linha:http://hdl.handle.net/10261/151628
Access Level:acceso abierto
Palavra-chave:crystal structure
1,5-benzodiazepine
benzo[b][1,4]dia-][1,4]diazepine
Descrição
Resumo:The title compound, C11H12N2, is not planar due to the folding of the seven-membered ring. In the crystal, molecules are packed opposite each other to minimize the electronic repulsion but the long intermolecular distances indicate that no directional contacts are found.