Increasing dimensionality in self‐assembly. Toward two‐dimensional supramolecular polymers

Different approaches to achieve 2D supramolecular polymers, as an alternative to the covalent bottom‐up approaches reported for the preparation of 2D materials, are reviewed. The significance of the operation of weak non‐covalent forces to induce a lateral growth of a number of self‐assembling units...

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Detalhes bibliográficos
Autores: Atienza Castellanos, Carmen María, Sánchez Martín, Luis
Formato: artículo
Fecha de publicación:2024
País:España
Recursos:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/102623
Acesso em linha:https://hdl.handle.net/20.500.14352/102623
Access Level:acceso abierto
Palavra-chave:547
Química orgánica (Química)
2306 Química Orgánica
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spelling Increasing dimensionality in self‐assembly. Toward two‐dimensional supramolecular polymersAtienza Castellanos, Carmen MaríaSánchez Martín, Luis547Química orgánica (Química)2306 Química OrgánicaDifferent approaches to achieve 2D supramolecular polymers, as an alternative to the covalent bottom‐up approaches reported for the preparation of 2D materials, are reviewed. The significance of the operation of weak non‐covalent forces to induce a lateral growth of a number of self‐assembling units is collected. The examples of both thermodynamically and kinetically controlled formation of 2D supramolecular polymers showed in this review demonstrate the utility of this strategy to achieve new 2D materials with biased morphologies (nanosheets, scrolls, porous surfaces) and showing elegant applications like chiral recognition, enantioselective uptake or asymmetric organic transformations. Furthermore, elaborated techniques like seeded or living supramolecular polymerizations have been demonstrated to give rise to complex 2D nanostructures.Universidad Complutense de Madrid20242024-03-2520242024-03-25journal articlehttp://purl.org/coar/resource_type/c_6501info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/20.500.14352/102623reponame:Docta Complutenseinstname:Universidad Complutense de Madrid (UCM)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:docta.ucm.es:20.500.14352/1026232026-06-02T12:44:21Z
dc.title.none.fl_str_mv Increasing dimensionality in self‐assembly. Toward two‐dimensional supramolecular polymers
title Increasing dimensionality in self‐assembly. Toward two‐dimensional supramolecular polymers
spellingShingle Increasing dimensionality in self‐assembly. Toward two‐dimensional supramolecular polymers
Atienza Castellanos, Carmen María
547
Química orgánica (Química)
2306 Química Orgánica
title_short Increasing dimensionality in self‐assembly. Toward two‐dimensional supramolecular polymers
title_full Increasing dimensionality in self‐assembly. Toward two‐dimensional supramolecular polymers
title_fullStr Increasing dimensionality in self‐assembly. Toward two‐dimensional supramolecular polymers
title_full_unstemmed Increasing dimensionality in self‐assembly. Toward two‐dimensional supramolecular polymers
title_sort Increasing dimensionality in self‐assembly. Toward two‐dimensional supramolecular polymers
dc.creator.none.fl_str_mv Atienza Castellanos, Carmen María
Sánchez Martín, Luis
author Atienza Castellanos, Carmen María
author_facet Atienza Castellanos, Carmen María
Sánchez Martín, Luis
author_role author
author2 Sánchez Martín, Luis
author2_role author
dc.contributor.none.fl_str_mv Universidad Complutense de Madrid
dc.subject.none.fl_str_mv 547
Química orgánica (Química)
2306 Química Orgánica
topic 547
Química orgánica (Química)
2306 Química Orgánica
description Different approaches to achieve 2D supramolecular polymers, as an alternative to the covalent bottom‐up approaches reported for the preparation of 2D materials, are reviewed. The significance of the operation of weak non‐covalent forces to induce a lateral growth of a number of self‐assembling units is collected. The examples of both thermodynamically and kinetically controlled formation of 2D supramolecular polymers showed in this review demonstrate the utility of this strategy to achieve new 2D materials with biased morphologies (nanosheets, scrolls, porous surfaces) and showing elegant applications like chiral recognition, enantioselective uptake or asymmetric organic transformations. Furthermore, elaborated techniques like seeded or living supramolecular polymerizations have been demonstrated to give rise to complex 2D nanostructures.
publishDate 2024
dc.date.none.fl_str_mv 2024
2024-03-25
2024
2024-03-25
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/20.500.14352/102623
url https://hdl.handle.net/20.500.14352/102623
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Docta Complutense
instname:Universidad Complutense de Madrid (UCM)
instname_str Universidad Complutense de Madrid (UCM)
reponame_str Docta Complutense
collection Docta Complutense
repository.name.fl_str_mv
repository.mail.fl_str_mv
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