Large-Size Star-Shaped Conjugated (Fused) Triphthalocyaninehexaazatriphenylene

Star-shaped triphthalocyaninehexaazatriphenylene 1 was synthesized via condensation between a new building block 1,2-diaminophthalocyanine and cyclohexanehexaone. Compound 1 represents the largest star-shaped phthalocyanine-fused hexaazatriphenylene reported so far. This largely expanded phthalocyan...

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Detalhes bibliográficos
Autores: Blas-Ferrando, Vicente M., Ortiz, Javier, Follana-Berná, Jorge, Fernández-Lázaro, Fernando, Campos García, Antonio, Mas Torrent, Marta, Sastre-Santos, Ángela
Tipo de documento: artigo
Estado:Versión aceptada para publicación
Data de publicação:2016
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositório:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/134339
Acesso em linha:http://hdl.handle.net/10261/134339
Access Level:Acceso aberto
Palavra-chave:Thin-film transistors
Organic semiconductors
Charge-transfer
Hydrogen-bonds
Transport
Electron
Derivatives
Electroluminiscence
Phthalocyanines
Molecules
Descrição
Resumo:Star-shaped triphthalocyaninehexaazatriphenylene 1 was synthesized via condensation between a new building block 1,2-diaminophthalocyanine and cyclohexanehexaone. Compound 1 represents the largest star-shaped phthalocyanine-fused hexaazatriphenylene reported so far. This largely expanded phthalocyanine shows good solubility and has a strong tendency to aggregate in both solution and on surface, indicating its potential as active component in organic electronic devices.

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