Visible-light photoelectrodegradation of diuron on WO3 nanostructures

[EN] The degradation of pesticide diuron has been explored by photoelectrocatalysis (PEC) under visible light illumination using two different WO3 nanostructures, obtained by anodization of tungsten. The highest degradation efficiency (73%) was obtained for WO3 nanosheets synthesized in the presence...

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Detalhes bibliográficos
Autores: Fernández Domene, Ramón Manuel, Sánchez Tovar, Rita, Lucas-Granados, Bianca, Ramírez-Grau, R., Muñoz-Portero, María-José|||0000-0002-7407-2598, Garcia-Anton, Jose|||0000-0002-0289-1324
Tipo de documento: artigo
Data de publicação:2018
País:España
Recursos:Universitat Politècnica de València (UPV)
Repositório:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglês
OAI Identifier:oai:riunet.upv.es:10251/120695
Acesso em linha:https://riunet.upv.es/handle/10251/120695
Access Level:Acceso aberto
Palavra-chave:Photoelectrocatalysis
WO3 nanostructures, Anodization
Diuron
Pesticides
INGENIERIA QUIMICA
Descrição
Resumo:[EN] The degradation of pesticide diuron has been explored by photoelectrocatalysis (PEC) under visible light illumination using two different WO3 nanostructures, obtained by anodization of tungsten. The highest degradation efficiency (73%) was obtained for WO3 nanosheets synthesized in the presence of small amounts of hydrogen peroxide (0.05 M). For that nanostructure, the kinetic coefficient for diuron degradation was 133% higher than that for the other nanostructure (anodized in the presence of fluoride anions). These results have been explained by taking into account the different architecture and dimensions of the two WO3 nanostructures under study.