Octahedral Tantalum Bromide Clusters as Catalysts for Light-Driven Hydrogen Evolution

[EN] Octahedral tantalum clusters are redox-active compounds. [{Ta6Bri12}Bra2(H2O)a4]·4H2O (i = inner; a = apical ligands) cluster results in efficient pre-catalyst for the light-driven H2 production from aqueous protons in homogeneous conditions. The most active cluster species are in situ generate...

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Detalhes bibliográficos
Autores: Hernandez-Niño, Jhon Sebastian|||0000-0002-6550-7107, Feliz Rodriguez, Marta|||0000-0002-4429-0551, Guevara, Daniela, Shamsurin, Maxim, Benassi, Enrico, Sokolov, Maxim N.
Tipo de documento: artigo
Data de publicação:2023
País:España
Recursos:Universitat Politècnica de València (UPV)
Repositório:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglês
OAI Identifier:oai:riunet.upv.es:10251/205210
Acesso em linha:https://riunet.upv.es/handle/10251/205210
Access Level:Acceso aberto
Palavra-chave:Alcohols
Cluster chemistry
Evolution reactions
Hydrogen
Metal clusters
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Descrição
Resumo:[EN] Octahedral tantalum clusters are redox-active compounds. [{Ta6Bri12}Bra2(H2O)a4]·4H2O (i = inner; a = apical ligands) cluster results in efficient pre-catalyst for the light-driven H2 production from aqueous protons in homogeneous conditions. The most active cluster species are in situ generated by apical ligand exchange reaction from aqueous media.

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