Asymmetric Catalytic Transformations of Aza-ortho- and Aza-para-Quinone Methides
The catalytic methodologies for the derivatization of aza-QM have recently appeared in the literature and involve organocatalytic and organometallic approaches. This review aims at analyzing the diverse catalytic systems involving chiral NHC carbenes, phosphoric acids, phosphoramidites, phosphine an...
| Autores: | , |
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| Tipo de documento: | artigo |
| Data de publicação: | 2023 |
| País: | España |
| Recursos: | Universidad de Alcalá (UAH) |
| Repositório: | e_Buah Biblioteca Digital Universidad de Alcalá |
| Idioma: | inglês |
| OAI Identifier: | oai:ebuah.uah.es:10017/57912 |
| Acesso em linha: | http://hdl.handle.net/10017/57912 https://dx.doi.org/10.1002/cctc.202300500 |
| Access Level: | Acceso aberto |
| Palavra-chave: | asymmetric synthesis aza-ortho-quinone methides aza-para-quinone methides metal catalysis organocatalysis Química Chemistry |
| Resumo: | The catalytic methodologies for the derivatization of aza-QM have recently appeared in the literature and involve organocatalytic and organometallic approaches. This review aims at analyzing the diverse catalytic systems involving chiral NHC carbenes, phosphoric acids, phosphoramidites, phosphine and copper and palladium catalysis showing its applicability for the synthesis of a diverse away of N-containing compounds which in many cases have biological activity. |
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