Synthetic applications of intramolecular aza-Wittig reaction for the preparation of heterocyclic compound

[EN] A review focused on recent advances in intramolecular aza-Wittig reaction of phosphazenes with several carbonyl or analogous compounds is reported. Phosphazenes afford intramolecular aza-Wittig reaction with different groups within the molecule as aldehydes, ketones, esters, thioesters, amides,...

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Bibliographic Details
Authors: Palacios Gambra, Francisco Javier, Aparicio Gutiérrez, Domitila, Rubiales Alcaine, María Gloria, Alonso Pérez, Concepción Estibaliz, De Los Santos Ruiz, Jesús Manuel
Format: article
Publication Date:2009
Country:España
Institution:Universidad del País Vasco
Repository:Addi. Archivo Digital para la Docencia y la Investigación
OAI Identifier:oai:addi.ehu.eus:10810/17409
Online Access:http://hdl.handle.net/10810/17409
Access Level:Open access
Keyword:intramolecular aza-Wittig reaction
heterocyclic compounds
phosphazenes
carbonyl compounds
reacción intramolecular aza-Wittig
compuestos heterocíclicos
fosfacenos
compuestos carbonílicos
CHEMISTRY, ORGANIC
Description
Summary:[EN] A review focused on recent advances in intramolecular aza-Wittig reaction of phosphazenes with several carbonyl or analogous compounds is reported. Phosphazenes afford intramolecular aza-Wittig reaction with different groups within the molecule as aldehydes, ketones, esters, thioesters, amides, anhydrides and sulfimides. One of the most important applications of this reaction is the synthesis of a wide range of heterocyclic compounds, ranging from simple monocyclic compounds to complex polycyclic and macrocyclic systems.

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