Rapid and sensitive method for the simultaneous determination of PAHs and alkyl-PAHs in scrubber water using HS-SPME-GC-MS/MS

Scrubber water, a waste stream generated by ships exhaust gas cleaning systems, may pose a threat when released into the marine environment due to potential contamination with poly- cyclic aromatic hydrocarbons (PAHs) and their alkyl derivatives (alkyl-PAHs). This study aims to develop a reliable an...

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Detalhes bibliográficos
Autores: García-Gómez, Elisa, Insa Aguilar, Sara, Gros Calvo, Meritxell, Petrović, Mira
Tipo de documento: artigo
Estado:Versão publicada
Data de publicação:2024
País:España
Recursos:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositório:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:10256/26844
Acesso em linha:http://hdl.handle.net/10256/26844
Access Level:Acceso aberto
Palavra-chave:Mar -- Contaminació
Marine pollution
Mar -- Contaminació per hidrocarburs
Oil pollution of the sea
Contaminants emergents en l'aigua
Emerging contaminants in water
Vaixells -- Aspectes ambientals
Ships -- Environmental aspects
Hidrocarburs aromàtics policíclics
Polycyclic aromatic hydrocarbons
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spelling Rapid and sensitive method for the simultaneous determination of PAHs and alkyl-PAHs in scrubber water using HS-SPME-GC-MS/MSGarcía-Gómez, ElisaInsa Aguilar, SaraGros Calvo, MeritxellPetrović, MiraMar -- ContaminacióMarine pollutionMar -- Contaminació per hidrocarbursOil pollution of the seaContaminants emergents en l'aiguaEmerging contaminants in waterVaixells -- Aspectes ambientalsShips -- Environmental aspectsHidrocarburs aromàtics policíclicsPolycyclic aromatic hydrocarbonsScrubber water, a waste stream generated by ships exhaust gas cleaning systems, may pose a threat when released into the marine environment due to potential contamination with poly- cyclic aromatic hydrocarbons (PAHs) and their alkyl derivatives (alkyl-PAHs). This study aims to develop a reliable analytical procedure combining headspace solid-phase microextraction (HS- SPME) with gas chromatography coupled to triple quadrupole tandem mass spectrometry (GC-MS/MS) to simultaneously separate and determine target compounds in aqueous samples. Method validation demonstrated good linearity up to 200 ng L− 1 (r2 > 0.996) and low limits of detection (0.33 to 1.67 ng L− 1 , except for naphthalene at 3.3 ng L− 1 ). The method shows good precision (RSD < 20%) and satisfactory analytical recoveries. The methodology was successfully applied to scrubber water samples collected from a container ship and the results highlight the prevalence of naphthalene, phenanthrene, and their alkyl derivatives. Rapid and reproducible HS-SPME-GC-MS/MS method for the analysis of PAHs and alkyl-PAHs in scrubber water. The capacity of SPME to analyze both filtered and unfiltered samples was assessed, showing that the more hydrophobic PAHs may be lost during filtrationThis study has been funded by the Horizon 2020 project EMERGE (Grant agreement ID: 874990). The authors are grateful to the company Danaos, and the researchers Leonidas Ntziachristos (Aristotle University of Thessaloniki, Greece), Andreas Gondikas (Creative Nano, Greece), Jana Moldanova (IVL, Sweden), Anna Lunde Hermansson and Erik Ytreberg (Chalmers University), and the whole team planning the field campaign for providing scrubber water samples, and to Maria Granberg and Kerstin Magnusson for highlighting the importance of alkyl-PAHs as target compounds in scrubber water. Meritxell Gros acknowledges her Ramon y Cajal contract (RYC2020-030324-I) funded by the MCIN/AEI 10.13039/501100011033 and by “ESF Investing in your future”. Authors also acknowledge the European Regional Development Fund (FEDER), the Generalitat de Catalunya through the Consolidated Research Group (SGR ICRA-ENV 2021 01282) and the funding from CERCA program. The Gas Chromatograph coupled a triple quadrupole Mass Spectrometer system (GC–MS/MS) received support from the CERCA Institute through the CERCAGINYS program, funded by the Spanish Ministry of Science and InnovationElsevier2024info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionpeer reviewedapplication/pdfhttp://hdl.handle.net/10256/26844http://hdl.handle.net/10256/26844MethodsX, 2024, vol. 12, art.núm.102589Articles publicats (ICRA)García-Gómez, Elisa nsa Aguilar, Sara Gros Calvo, Meritxell Petrovi&#263, Mira 2024 Rapid and sensitive method for the simultaneous determination of PAHs and alkyl-PAHs in scrubber water using HS-SPME-GC-MS/MS MethodsX 12 art.núm.102589reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)Inglésinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.mex.2024.102589info:eu-repo/semantics/altIdentifier/issn/2215-0161info:eu-repo/semantics/altIdentifier/eissn/2215-0161Reconeixement-NoComercial-SenseObraDerivada 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc-nd/4.0info:eu-repo/semantics/openAccessoai:recercat.cat:10256/268442026-05-29T05:05:01Z
dc.title.none.fl_str_mv Rapid and sensitive method for the simultaneous determination of PAHs and alkyl-PAHs in scrubber water using HS-SPME-GC-MS/MS
title Rapid and sensitive method for the simultaneous determination of PAHs and alkyl-PAHs in scrubber water using HS-SPME-GC-MS/MS
spellingShingle Rapid and sensitive method for the simultaneous determination of PAHs and alkyl-PAHs in scrubber water using HS-SPME-GC-MS/MS
García-Gómez, Elisa
Mar -- Contaminació
Marine pollution
Mar -- Contaminació per hidrocarburs
Oil pollution of the sea
Contaminants emergents en l'aigua
Emerging contaminants in water
Vaixells -- Aspectes ambientals
Ships -- Environmental aspects
Hidrocarburs aromàtics policíclics
Polycyclic aromatic hydrocarbons
title_short Rapid and sensitive method for the simultaneous determination of PAHs and alkyl-PAHs in scrubber water using HS-SPME-GC-MS/MS
title_full Rapid and sensitive method for the simultaneous determination of PAHs and alkyl-PAHs in scrubber water using HS-SPME-GC-MS/MS
title_fullStr Rapid and sensitive method for the simultaneous determination of PAHs and alkyl-PAHs in scrubber water using HS-SPME-GC-MS/MS
title_full_unstemmed Rapid and sensitive method for the simultaneous determination of PAHs and alkyl-PAHs in scrubber water using HS-SPME-GC-MS/MS
title_sort Rapid and sensitive method for the simultaneous determination of PAHs and alkyl-PAHs in scrubber water using HS-SPME-GC-MS/MS
dc.creator.none.fl_str_mv García-Gómez, Elisa
Insa Aguilar, Sara
Gros Calvo, Meritxell
Petrović, Mira
author García-Gómez, Elisa
author_facet García-Gómez, Elisa
Insa Aguilar, Sara
Gros Calvo, Meritxell
Petrović, Mira
author_role author
author2 Insa Aguilar, Sara
Gros Calvo, Meritxell
Petrović, Mira
author2_role author
author
author
dc.subject.none.fl_str_mv Mar -- Contaminació
Marine pollution
Mar -- Contaminació per hidrocarburs
Oil pollution of the sea
Contaminants emergents en l'aigua
Emerging contaminants in water
Vaixells -- Aspectes ambientals
Ships -- Environmental aspects
Hidrocarburs aromàtics policíclics
Polycyclic aromatic hydrocarbons
topic Mar -- Contaminació
Marine pollution
Mar -- Contaminació per hidrocarburs
Oil pollution of the sea
Contaminants emergents en l'aigua
Emerging contaminants in water
Vaixells -- Aspectes ambientals
Ships -- Environmental aspects
Hidrocarburs aromàtics policíclics
Polycyclic aromatic hydrocarbons
description Scrubber water, a waste stream generated by ships exhaust gas cleaning systems, may pose a threat when released into the marine environment due to potential contamination with poly- cyclic aromatic hydrocarbons (PAHs) and their alkyl derivatives (alkyl-PAHs). This study aims to develop a reliable analytical procedure combining headspace solid-phase microextraction (HS- SPME) with gas chromatography coupled to triple quadrupole tandem mass spectrometry (GC-MS/MS) to simultaneously separate and determine target compounds in aqueous samples. Method validation demonstrated good linearity up to 200 ng L− 1 (r2 > 0.996) and low limits of detection (0.33 to 1.67 ng L− 1 , except for naphthalene at 3.3 ng L− 1 ). The method shows good precision (RSD < 20%) and satisfactory analytical recoveries. The methodology was successfully applied to scrubber water samples collected from a container ship and the results highlight the prevalence of naphthalene, phenanthrene, and their alkyl derivatives. Rapid and reproducible HS-SPME-GC-MS/MS method for the analysis of PAHs and alkyl-PAHs in scrubber water. The capacity of SPME to analyze both filtered and unfiltered samples was assessed, showing that the more hydrophobic PAHs may be lost during filtration
publishDate 2024
dc.date.none.fl_str_mv 2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
peer reviewed
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10256/26844
http://hdl.handle.net/10256/26844
url http://hdl.handle.net/10256/26844
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.mex.2024.102589
info:eu-repo/semantics/altIdentifier/issn/2215-0161
info:eu-repo/semantics/altIdentifier/eissn/2215-0161
dc.rights.none.fl_str_mv Reconeixement-NoComercial-SenseObraDerivada 4.0 Internacional
http://creativecommons.org/licenses/by-nc-nd/4.0
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Reconeixement-NoComercial-SenseObraDerivada 4.0 Internacional
http://creativecommons.org/licenses/by-nc-nd/4.0
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv MethodsX, 2024, vol. 12, art.núm.102589
Articles publicats (ICRA)
García-Gómez, Elisa nsa Aguilar, Sara Gros Calvo, Meritxell Petrovi&#263, Mira 2024 Rapid and sensitive method for the simultaneous determination of PAHs and alkyl-PAHs in scrubber water using HS-SPME-GC-MS/MS MethodsX 12 art.núm.102589
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.812455

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