Ru Nanoparticles Supported on Mesoporous Al-SBA-15 Catalysts for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol

This is an open access article under the terms of the Creative Commons Attribution Non-Commercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.

Bibliographic Details
Authors: Kumaravel, Sakthivel, Durai, Mani, Kaliyamoorthy, Selvam, Kumaravel, Saranraj, Chandramoorthy, Chandrasatheesh, Avula, Balakrishna, Hasan, Imran, Balu, Krishnakumar, Ahn, Young Ho
Format: article
Status:Published version
Publication Date:2023
Country:España
Institution:Universidad de Sevilla (US)
Repository:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/149721
Online Access:https://hdl.handle.net/11441/149721
https://doi.org/10.1002/slct.202301787
Access Level:Open access
Keyword:Furfural
Furfuryl alcohol
Hydrogenation
Mesoporous catalyst
Ru/Al-SBA-15
id ES_7574bcaf497e867a1d57f9ddfa8c8db9
oai_identifier_str oai:idus.us.es:11441/149721
network_acronym_str ES
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spelling Ru Nanoparticles Supported on Mesoporous Al-SBA-15 Catalysts for Highly Selective Hydrogenation of Furfural to Furfuryl AlcoholKumaravel, SakthivelDurai, ManiKaliyamoorthy, SelvamKumaravel, SaranrajChandramoorthy, ChandrasatheeshAvula, BalakrishnaHasan, ImranBalu, KrishnakumarAhn, Young HoFurfuralFurfuryl alcoholHydrogenationMesoporous catalystRu/Al-SBA-15This is an open access article under the terms of the Creative Commons Attribution Non-Commercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.Furfuryl alcohol, which is the hydrogenated product of furfural, has been identified as a very promising platform chemical with high potential for applications in the manufacture of key chemicals, lubricants, fragrances, and pharmaceuticals. In this work, bare SB, and x % Ru/Al-SB (x=1.5, 2.5, 3.5, and 4.5 wt. %) samples were fabricated by a hydrothermal method. Bare and most active catalysts were characterized by different techniques, such as BET, FE-SEM, TEM, FT-IR, and XRD, to understand their physical and chemical properties. An evaluation of the effects of various reaction parameters, such as catalyst loading, reaction temperature, and reaction time, on the catalytic performance, showed higher catalytic conversion of furfural and selectivity for the desired products. The most active RuS3 catalyst showed 100 % conversion of furfural and 99 % selectivity for furfuryl alcohol. It could be reused for five consecutive reaction cycles without significant loss of performance. In addition, Ru leaching and loss of conversion or selectivity were not noticed during the five-run recycling test. The EDS elemental mapping analysis of the used catalyst established the preservation of the mesoporous structure, suggesting a strong interaction between the hexagonal porous silicate and the Ru nanoparticles.WileyIngeniería y Ciencia de los Materiales y del TransporteTEP973: Tecnología de Polvos y CorrosiónUniversidad Rey Saúd. Arabia SauditaMinisterio de Comercio, Industria y Energía. República de Corea.Ministerio de Océanos y Pesca. República de Corea.Ministerio de Educación. República de Corea.2023info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfapplication/pdfhttps://hdl.handle.net/11441/149721https://doi.org/10.1002/slct.202301787reponame:idUS. Depósito de Investigación de la Universidad de Sevillainstname:Universidad de Sevilla (US)InglésChemistrySelect, 8 (34), e202301787.RSPD2023R67020225B10300100202201492020R1I1A305481611https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/slct.202301787info:eu-repo/semantics/openAccessoai:idus.us.es:11441/1497212026-06-17T12:51:07Z
dc.title.none.fl_str_mv Ru Nanoparticles Supported on Mesoporous Al-SBA-15 Catalysts for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol
title Ru Nanoparticles Supported on Mesoporous Al-SBA-15 Catalysts for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol
spellingShingle Ru Nanoparticles Supported on Mesoporous Al-SBA-15 Catalysts for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol
Kumaravel, Sakthivel
Furfural
Furfuryl alcohol
Hydrogenation
Mesoporous catalyst
Ru/Al-SBA-15
title_short Ru Nanoparticles Supported on Mesoporous Al-SBA-15 Catalysts for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol
title_full Ru Nanoparticles Supported on Mesoporous Al-SBA-15 Catalysts for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol
title_fullStr Ru Nanoparticles Supported on Mesoporous Al-SBA-15 Catalysts for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol
title_full_unstemmed Ru Nanoparticles Supported on Mesoporous Al-SBA-15 Catalysts for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol
title_sort Ru Nanoparticles Supported on Mesoporous Al-SBA-15 Catalysts for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol
dc.creator.none.fl_str_mv Kumaravel, Sakthivel
Durai, Mani
Kaliyamoorthy, Selvam
Kumaravel, Saranraj
Chandramoorthy, Chandrasatheesh
Avula, Balakrishna
Hasan, Imran
Balu, Krishnakumar
Ahn, Young Ho
author Kumaravel, Sakthivel
author_facet Kumaravel, Sakthivel
Durai, Mani
Kaliyamoorthy, Selvam
Kumaravel, Saranraj
Chandramoorthy, Chandrasatheesh
Avula, Balakrishna
Hasan, Imran
Balu, Krishnakumar
Ahn, Young Ho
author_role author
author2 Durai, Mani
Kaliyamoorthy, Selvam
Kumaravel, Saranraj
Chandramoorthy, Chandrasatheesh
Avula, Balakrishna
Hasan, Imran
Balu, Krishnakumar
Ahn, Young Ho
author2_role author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Ingeniería y Ciencia de los Materiales y del Transporte
TEP973: Tecnología de Polvos y Corrosión
Universidad Rey Saúd. Arabia Saudita
Ministerio de Comercio, Industria y Energía. República de Corea.
Ministerio de Océanos y Pesca. República de Corea.
Ministerio de Educación. República de Corea.
dc.subject.none.fl_str_mv Furfural
Furfuryl alcohol
Hydrogenation
Mesoporous catalyst
Ru/Al-SBA-15
topic Furfural
Furfuryl alcohol
Hydrogenation
Mesoporous catalyst
Ru/Al-SBA-15
description This is an open access article under the terms of the Creative Commons Attribution Non-Commercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
publishDate 2023
dc.date.none.fl_str_mv 2023
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/11441/149721
https://doi.org/10.1002/slct.202301787
url https://hdl.handle.net/11441/149721
https://doi.org/10.1002/slct.202301787
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv ChemistrySelect, 8 (34), e202301787.
RSPD2023R670
20225B10300100
20220149
2020R1I1A305481611
https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/slct.202301787
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:idUS. Depósito de Investigación de la Universidad de Sevilla
instname:Universidad de Sevilla (US)
instname_str Universidad de Sevilla (US)
reponame_str idUS. Depósito de Investigación de la Universidad de Sevilla
collection idUS. Depósito de Investigación de la Universidad de Sevilla
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,301629

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