Multiphase Diagenetic Processes and Their Impact on Reservoir Character of the Late Triassic (Rhaetian) Kingriali Formation, Upper Indus Basin, Pakistan

<p><span style="color:rgb( 46 , 46 , 46 )">Multiple episodes of dolomitization of the shallow marine carbonates of the Late Kingriali Formation resulted in regional scale mappable dolostone geobodies in the Kohat and Potwar sub-basins. With the exception of few unaltered patche...

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Autores: Ahmad, Imran, Shah, Mumtaz Muhammad, Janjuhah, Hammad Tariq, Travé i Herrero, Anna, Antonarakou, Assimina, Kontakiotis, George
Tipo de documento: artigo
Estado:Versão publicada
Data de publicação:2022
País:España
Recursos:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositório:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/205990
Acesso em linha:https://hdl.handle.net/2445/205990
Access Level:Acceso aberto
Palavra-chave:Geoquímica
Petrologia
Geochemistry
Petrology
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spelling Multiphase Diagenetic Processes and Their Impact on Reservoir Character of the Late Triassic (Rhaetian) Kingriali Formation, Upper Indus Basin, PakistanAhmad, ImranShah, Mumtaz MuhammadJanjuhah, Hammad TariqTravé i Herrero, AnnaAntonarakou, AssiminaKontakiotis, GeorgeGeoquímicaPetrologiaGeochemistryPetrology<p><span style="color:rgb( 46 , 46 , 46 )">Multiple episodes of dolomitization of the shallow marine carbonates of the Late Kingriali Formation resulted in regional scale mappable dolostone geobodies in the Kohat and Potwar sub-basins. With the exception of few unaltered patches of the host limestone, more than 90% of the carbonates of the studied formation are diagenetically altered by replacive dolomites with associated dolomite cementation. Petrographical and geochemical data interpretation reveals that during the initial stage of dolomitization, the precursor limestone was significantly modified by the fabric-retentive replacive dolomite (RD-I) and produced bulk dolostones with non-planar-a to planar-s crystals. Neomorphic recrystallization (RD-II) was observed as an overgrowth of the already formed RD-I dolomite crystals during progressive dolomitization. The seawater at shallow depths is enriched with Fe-ions due to its interaction with Fe-rich beds within the studied formation. The modified seawater actively participated in the formation of ferroan replacive dolomites (RD-III). Stable isotopic composition of the unaltered Echinoderm plates, calcite cement (CC-I), and RD-I demonstrates signatures of δ18O and δ13C within the limit of late Triassic marine seawater or modified seawater. Depletion in the stable oxygen isotopic composition (from −0.99‰ to −3.75‰ V-PDB) demonstrates that RD-II and RD-III were formed in a sequence with progressively higher temperature fluids than normal seawater. Precipitation of dolomite cements as cavity filling rhombs (DC-I) and crystal overgrowth (DC-II) with highly depleted δ18O values (−5.44‰ to −7.45‰ V-PDB) illustrates dolomite cementation at higher temperatures and greater depths. The highly depleted values of δ18O (up to −9.16‰ V-PDB) and (up to 0.42‰ V-PDB) for δ13C of saddle dolomite (SD-I) indicate the precipitation of SD-I as a cavity filling dolomite at considerable depth. Calcite cementation and calcitization actively participated in the early, middle, and late diagenetic modifications as interpreted from their petrographic and stable isotopic studies. Porosity enhancement is clearly demonstrated by dissolution, stylolization, fracturing, and replacement dolomitization. Dolomite and calcite cementation had a negative impact on the reservoir character and occluded the dolostone porosity to a greater extent. © 2022 by the authors.</span></p>MDPI2024202420222024info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersion31 p.application/pdfapplication/pdfhttps://hdl.handle.net/2445/205990Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)InglésReproducció del document publicat a: https://doi.org/10.3390/min12081049Minerals, 2022, vol. 12, num.8https://doi.org/10.3390/min12081049cc-by (c) Ahmad, I. et al., 2022http://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:recercat.cat:2445/2059902026-05-29T05:05:01Z
dc.title.none.fl_str_mv Multiphase Diagenetic Processes and Their Impact on Reservoir Character of the Late Triassic (Rhaetian) Kingriali Formation, Upper Indus Basin, Pakistan
title Multiphase Diagenetic Processes and Their Impact on Reservoir Character of the Late Triassic (Rhaetian) Kingriali Formation, Upper Indus Basin, Pakistan
spellingShingle Multiphase Diagenetic Processes and Their Impact on Reservoir Character of the Late Triassic (Rhaetian) Kingriali Formation, Upper Indus Basin, Pakistan
Ahmad, Imran
Geoquímica
Petrologia
Geochemistry
Petrology
title_short Multiphase Diagenetic Processes and Their Impact on Reservoir Character of the Late Triassic (Rhaetian) Kingriali Formation, Upper Indus Basin, Pakistan
title_full Multiphase Diagenetic Processes and Their Impact on Reservoir Character of the Late Triassic (Rhaetian) Kingriali Formation, Upper Indus Basin, Pakistan
title_fullStr Multiphase Diagenetic Processes and Their Impact on Reservoir Character of the Late Triassic (Rhaetian) Kingriali Formation, Upper Indus Basin, Pakistan
title_full_unstemmed Multiphase Diagenetic Processes and Their Impact on Reservoir Character of the Late Triassic (Rhaetian) Kingriali Formation, Upper Indus Basin, Pakistan
title_sort Multiphase Diagenetic Processes and Their Impact on Reservoir Character of the Late Triassic (Rhaetian) Kingriali Formation, Upper Indus Basin, Pakistan
dc.creator.none.fl_str_mv Ahmad, Imran
Shah, Mumtaz Muhammad
Janjuhah, Hammad Tariq
Travé i Herrero, Anna
Antonarakou, Assimina
Kontakiotis, George
author Ahmad, Imran
author_facet Ahmad, Imran
Shah, Mumtaz Muhammad
Janjuhah, Hammad Tariq
Travé i Herrero, Anna
Antonarakou, Assimina
Kontakiotis, George
author_role author
author2 Shah, Mumtaz Muhammad
Janjuhah, Hammad Tariq
Travé i Herrero, Anna
Antonarakou, Assimina
Kontakiotis, George
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Geoquímica
Petrologia
Geochemistry
Petrology
topic Geoquímica
Petrologia
Geochemistry
Petrology
description <p><span style="color:rgb( 46 , 46 , 46 )">Multiple episodes of dolomitization of the shallow marine carbonates of the Late Kingriali Formation resulted in regional scale mappable dolostone geobodies in the Kohat and Potwar sub-basins. With the exception of few unaltered patches of the host limestone, more than 90% of the carbonates of the studied formation are diagenetically altered by replacive dolomites with associated dolomite cementation. Petrographical and geochemical data interpretation reveals that during the initial stage of dolomitization, the precursor limestone was significantly modified by the fabric-retentive replacive dolomite (RD-I) and produced bulk dolostones with non-planar-a to planar-s crystals. Neomorphic recrystallization (RD-II) was observed as an overgrowth of the already formed RD-I dolomite crystals during progressive dolomitization. The seawater at shallow depths is enriched with Fe-ions due to its interaction with Fe-rich beds within the studied formation. The modified seawater actively participated in the formation of ferroan replacive dolomites (RD-III). Stable isotopic composition of the unaltered Echinoderm plates, calcite cement (CC-I), and RD-I demonstrates signatures of δ18O and δ13C within the limit of late Triassic marine seawater or modified seawater. Depletion in the stable oxygen isotopic composition (from −0.99‰ to −3.75‰ V-PDB) demonstrates that RD-II and RD-III were formed in a sequence with progressively higher temperature fluids than normal seawater. Precipitation of dolomite cements as cavity filling rhombs (DC-I) and crystal overgrowth (DC-II) with highly depleted δ18O values (−5.44‰ to −7.45‰ V-PDB) illustrates dolomite cementation at higher temperatures and greater depths. The highly depleted values of δ18O (up to −9.16‰ V-PDB) and (up to 0.42‰ V-PDB) for δ13C of saddle dolomite (SD-I) indicate the precipitation of SD-I as a cavity filling dolomite at considerable depth. Calcite cementation and calcitization actively participated in the early, middle, and late diagenetic modifications as interpreted from their petrographic and stable isotopic studies. Porosity enhancement is clearly demonstrated by dissolution, stylolization, fracturing, and replacement dolomitization. Dolomite and calcite cementation had a negative impact on the reservoir character and occluded the dolostone porosity to a greater extent. © 2022 by the authors.</span></p>
publishDate 2022
dc.date.none.fl_str_mv 2022
2024
2024
2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/2445/205990
url https://hdl.handle.net/2445/205990
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Reproducció del document publicat a: https://doi.org/10.3390/min12081049
Minerals, 2022, vol. 12, num.8
https://doi.org/10.3390/min12081049
dc.rights.none.fl_str_mv cc-by (c) Ahmad, I. et al., 2022
http://creativecommons.org/licenses/by/4.0/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv cc-by (c) Ahmad, I. et al., 2022
http://creativecommons.org/licenses/by/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 31 p.
application/pdf
application/pdf
dc.publisher.none.fl_str_mv MDPI
publisher.none.fl_str_mv MDPI
dc.source.none.fl_str_mv Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
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