Supramolecular synthesis with N-hetero-tolanes: liquid crystals and hydrogen-bonded and halogen-bonded co-crystals

Different co-crystals from N-hetero-tolane derivatives are prepared by hydrogen- or halogen-bonding. Their crystal structures have been determined by single crystal X-ray diffraction (SCXRD). Highly ordered smectic liquid crystals are obtained upon protonation of compound 1 and show a remarkable the...

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Bibliographic Details
Authors: Flores, Linda, López Duarte, Ismael, Gómez-Lor, Berta, Gutierrez-Puebla, Enrique, Hennrich, Gunther
Format: article
Publication Date:2020
Country:España
Institution:Universidad Complutense de Madrid (UCM)
Repository:Docta Complutense
Language:English
OAI Identifier:oai:docta.ucm.es:20.500.14352/115741
Online Access:https://hdl.handle.net/20.500.14352/115741
Access Level:Open access
Keyword:615.31
615:54
Química farmaceútica
23 Química
Description
Summary:Different co-crystals from N-hetero-tolane derivatives are prepared by hydrogen- or halogen-bonding. Their crystal structures have been determined by single crystal X-ray diffraction (SCXRD). Highly ordered smectic liquid crystals are obtained upon protonation of compound 1 and show a remarkable thermal stability. All supramolecular aggregates, crystalline or liquid crystalline, are characterized accordingly by X-ray diffraction (XRD), polarized optical microscopy (POM), and thermal analysis (DSC)