Investigation of a new approach for 36 Cl determination in solid samples using plastic scintillators

This work reports a new approach for the determination of 36Cl in radioactive waste samples from nuclear decommissioning, wherein novel plastic scintillator (PS) materials were used for the concentration of 36 Cl prior to the detection with scintillation counting. Different plastic scintillator (PS)...

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Detalles Bibliográficos
Autores: Llopart Babot, Inés, Vasile, M., Tarancón Sanz, Alex, Bagán Navarro, Héctor, Dobney, A., Boden, Sven, Bruggeman, Michel, Leermakers, Martine, Qiao, Jixin, Warwick, Phillip E.
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2023
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:dnet:recercat____::95552bde9af3480b64407945aaeecf52
Acceso en línea:https://hdl.handle.net/2445/229429
Access Level:acceso abierto
Palabra clave:Piròlisi
Absorció
Cromatografia
Eliminació de residus radioactius
Pyrolysis
Absorption
Chromatography
Radioactive waste disposa
Descripción
Sumario:This work reports a new approach for the determination of 36Cl in radioactive waste samples from nuclear decommissioning, wherein novel plastic scintillator (PS) materials were used for the concentration of 36 Cl prior to the detection with scintillation counting. Different plastic scintillator (PS) materials were tested for their selective absorption and detection of 36Cl activity in solid samples. PS microspheres (PSm), cross-linked PSm (CPSm) and PS resin have been investigated. PS resin was identified as the most suitable material for 36 Cl analysis. Pyrolysis and subsequent trapping of the volatile elements in a bubbler was used. The trapping solution was finally loaded onto a cartridge of the PS resin. Scintillation counting and ion chromatography were used to determine the activity concentration and the chemical recovery, respectively.