Rapid Determination of Metribuzin and Three Major Transformation Products in Soil and Plant by Gas Chromatography–Tandem Mass Spectrometry

11 Pág.

Detalhes bibliográficos
Autores: Albero Romano, María Beatriz, Fernández, M. Dolores, García-Gómez, Concepción, Pérez Martín, Rosa Ana
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2022
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/305065
Acesso em linha:http://hdl.handle.net/10261/305065
https://api.elsevier.com/content/abstract/scopus_id/85144650357
Access Level:acceso abierto
Palavra-chave:Analysis
Bean
Desamino-diketo-metribuzin
Diketo-metribuzin
Desamino-metribuzin
Metabolites
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oai_identifier_str oai:digital.csic.es:10261/305065
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spelling Rapid Determination of Metribuzin and Three Major Transformation Products in Soil and Plant by Gas Chromatography–Tandem Mass SpectrometryAlbero Romano, María BeatrizFernández, M. DoloresGarcía-Gómez, ConcepciónPérez Martín, Rosa AnaAnalysisBeanDesamino-diketo-metribuzinDiketo-metribuzinDesamino-metribuzinMetabolites11 Pág.Metribuzin is a pre- and post-emergence triazinone herbicide used in a variety of crops. This herbicide is degraded in the environment into three major metabolites that have high water solubility, high to very high soil mobility, and low to moderate persistence in soil. This paper describes the development of an analytical method based on ultrasound-assisted extraction and GC-MS/MS determination for the determination metribuzin and its main metabolites in soil and plants. The developed method provided good recoveries for all compounds in soil and plants (from 73 to 121%). The quantitation limits obtained from plants (2.6 to 18 µg/kg) allow determining the presence of these compounds at trace levels. To evaluate the applicability of the developed methods, bean plants were grown in plastic pots with soil treated with metribuzin and collected after 23 days. At the end of the assay, only 11% of the initial concentration of metribuzin remained in soil. Metribuzin and its three metabolites were detected in plants, desamino-diketo-metribuzin is the most abundant metabolite. It is expected that the application of these methods can provide more data to monitor metribuzin residues due to herbicide treatments.This research was funded by the Community of Madrid (project S2018/BAA-4330) and by the Madrid Institute for Rural, Agriculture and Food Research and Development (IMIDRA) (project FP22 HERBI-RES)Peer reviewedMultidisciplinary Digital Publishing InstituteComunidad de MadridInstituto Madrileño de Investigación y Desarrollo Rural, Agrario y AlimentarioAlbero, Beatriz [0000-0002-6470-5232]Pérez Martín, Rosa Ana [0000-0001-8076-9167]Fernández, M. Dolores [0000-0003-2287-9506]García Gómez, Concepción [0000-0002-4518-4929]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202320232022info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/305065https://api.elsevier.com/content/abstract/scopus_id/85144650357reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE#S2018/BAA-4330Departamento de Medio Ambiente y Agronomía​https://doi.org/10.3390/separations9120386Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3050652026-05-22T06:33:51Z
dc.title.none.fl_str_mv Rapid Determination of Metribuzin and Three Major Transformation Products in Soil and Plant by Gas Chromatography–Tandem Mass Spectrometry
title Rapid Determination of Metribuzin and Three Major Transformation Products in Soil and Plant by Gas Chromatography–Tandem Mass Spectrometry
spellingShingle Rapid Determination of Metribuzin and Three Major Transformation Products in Soil and Plant by Gas Chromatography–Tandem Mass Spectrometry
Albero Romano, María Beatriz
Analysis
Bean
Desamino-diketo-metribuzin
Diketo-metribuzin
Desamino-metribuzin
Metabolites
title_short Rapid Determination of Metribuzin and Three Major Transformation Products in Soil and Plant by Gas Chromatography–Tandem Mass Spectrometry
title_full Rapid Determination of Metribuzin and Three Major Transformation Products in Soil and Plant by Gas Chromatography–Tandem Mass Spectrometry
title_fullStr Rapid Determination of Metribuzin and Three Major Transformation Products in Soil and Plant by Gas Chromatography–Tandem Mass Spectrometry
title_full_unstemmed Rapid Determination of Metribuzin and Three Major Transformation Products in Soil and Plant by Gas Chromatography–Tandem Mass Spectrometry
title_sort Rapid Determination of Metribuzin and Three Major Transformation Products in Soil and Plant by Gas Chromatography–Tandem Mass Spectrometry
dc.creator.none.fl_str_mv Albero Romano, María Beatriz
Fernández, M. Dolores
García-Gómez, Concepción
Pérez Martín, Rosa Ana
author Albero Romano, María Beatriz
author_facet Albero Romano, María Beatriz
Fernández, M. Dolores
García-Gómez, Concepción
Pérez Martín, Rosa Ana
author_role author
author2 Fernández, M. Dolores
García-Gómez, Concepción
Pérez Martín, Rosa Ana
author2_role author
author
author
dc.contributor.none.fl_str_mv Comunidad de Madrid
Instituto Madrileño de Investigación y Desarrollo Rural, Agrario y Alimentario
Albero, Beatriz [0000-0002-6470-5232]
Pérez Martín, Rosa Ana [0000-0001-8076-9167]
Fernández, M. Dolores [0000-0003-2287-9506]
García Gómez, Concepción [0000-0002-4518-4929]
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Analysis
Bean
Desamino-diketo-metribuzin
Diketo-metribuzin
Desamino-metribuzin
Metabolites
topic Analysis
Bean
Desamino-diketo-metribuzin
Diketo-metribuzin
Desamino-metribuzin
Metabolites
description 11 Pág.
publishDate 2022
dc.date.none.fl_str_mv 2022
2023
2023
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/305065
https://api.elsevier.com/content/abstract/scopus_id/85144650357
url http://hdl.handle.net/10261/305065
https://api.elsevier.com/content/abstract/scopus_id/85144650357
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
S2018/BAA-4330
Departamento de Medio Ambiente y Agronomía​
https://doi.org/10.3390/separations9120386
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869410134292168704
score 15,812455

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