Easily altered minerals and reequilibrated fluid inclusions provide extensive records of fluid and thermal history: gypsum pseudomorphs of the Tera Group, Tithonian-Berriasian, Cameros Basin

This study reports a complex fluid and thermal history using petrography, electron microprobe, isotopic analysisand fluid inclusions in replacement minerals within gypsum pseudomorphs in Tithonian-Berriasian lacustrine de-posits in Northern Spain. Limestones and dolostones, formed in the alkaline la...

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Detalhes bibliográficos
Autores: González Acebrón, Laura, Goldstein, Robert H., Arribas Mocoroa, José
Formato: artículo
Fecha de publicación:2012
País:España
Recursos:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/43082
Acesso em linha:https://hdl.handle.net/20.500.14352/43082
Access Level:acceso abierto
Palavra-chave:549.76
Fluid inclusions
Ypsum pseudomorphs
Cameros Basin
Thermal reequilibration.
Mineralogía (Geología)
2506.11 Mineralogía
Descrição
Resumo:This study reports a complex fluid and thermal history using petrography, electron microprobe, isotopic analysisand fluid inclusions in replacement minerals within gypsum pseudomorphs in Tithonian-Berriasian lacustrine de-posits in Northern Spain. Limestones and dolostones, formed in the alkaline lakes, contain lenticularly shapedgypsum pseudomorphs, considered to form in an evaporative lake. The gypsum was replaced by quartz andnon-ferroan calcite (Ca-2), which partially replaces the quartz. Quartz contains solid inclusions of a preexistingnon-ferroan calcite (Ca-1), anhydrite and celestine.High homogenization temperatures (Th) values and inconsistent thermometric behaviour within secondary fluidinclusion assemblages in quartz (147-351◦C) and calcite (108-352◦C) indicate high temperatures after precipita-tion and entrapment of lower temperature FIAs. Th are in the same range as other reequilibrated fluid inclusionsfrom quartz veins in the same area that are related to Cretaceous hydrothermalism.Gypsum was replaced by anhydrite, likely during early burial. Later, anhydrite was partially replaced by Ca-1associated with intermediate burial temperatures. Afterward, both anhydrite and Ca-1 were partially replacedby quartz and this by Ca-2. All were affected during higher temperature hydrothermalism and a CO2-H2O fluid.Progressive heating and hydrothermal pulses, involving a CO2-H2O fluid, produce the reequilibration of the FIAs,which was followed by uplift and cooling