Flame retardancy of wood-plastic composites by radiation-curing phosphorus-containing resins

Wood-plastic composites were prepared by impregnating softwood and tropical hardwood by a radiation-curing resin containing phosphorus or chlorine groups as flame retardant. Microscopic observations revealed that the heterogeneous impregnation depends on the density but also on the wood species and...

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Detalles Bibliográficos
Autores: Gibier, Maximilien, Lacoste, Clement, Corn, Stephane, Pucci, Monica Francesca, Trân, Quôc Khôi, Haurie Ibarra, Laia|||0000-0002-0732-8928, Sonnier, Rodolphe
Tipo de recurso: artículo
Fecha de publicación:2020
País:España
Institución:Universitat Politècnica de Catalunya (UPC)
Repositorio:UPCommons. Portal del coneixement obert de la UPC
Idioma:inglés
OAI Identifier:oai:upcommons.upc.edu:2117/177916
Acceso en línea:https://hdl.handle.net/2117/177916
https://dx.doi.org/10.1016/j.radphyschem.2019.108547
Access Level:acceso abierto
Palabra clave:Flammable materials
Heat -- Radiation and absorption
Fire prevention
Wood flammability
Radiation-curing
Phosphorus flame retardants
Materials inflamables
Calor -- Radiació i absorció
Incendis -- Prevenció
Àrees temàtiques de la UPC::Edificació::Materials de construcció::Fusta
Descripción
Sumario:Wood-plastic composites were prepared by impregnating softwood and tropical hardwood by a radiation-curing resin containing phosphorus or chlorine groups as flame retardant. Microscopic observations revealed that the heterogeneous impregnation depends on the density but also on the wood species and sample orientation. Physical properties (hardness, stiffness, conductivity, water content) of the unmodified woods and their resin-impregnated counterparts were examined and correlated with their densities. The flame retardancy was investigated by cone calorimeter tests. Although the incorporation of the resin is detrimental to the flame retardancy, the addition of phosphorus or chlorine groups allows a decrease in flammability. Phosphorus-containing resins limit the smoke release in comparison to chlorine-containing resin. Finally, the denser wood-plastic composites exhibit improved mechanical properties without increasing the flammability in comparison with their unmodified wood counterparts.