Occurrence and Origin of Andalusite in Peraluminous Felsic Igneous Rocks

Andalusite occurs as an accessory mineral in many types of peraluminous felsic igneous rocks, including rhyolites, aplites, granites, pegmatites, and anatectic migmatites. Some published stability curves for And = Sil and the water-saturated granite solidus permit a small stability field for andalus...

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Autores: Clarke, D. Barrie, Dorais, Michael, Barbarin, Bernard, Barker, Dan, Cesare, Bernardo, Clarke, Geoffrey, El Baghdadi, Mohamed, Erdmann, Saskia, Förster, Hans Jürger, Gaeta, Mario, Gottesmann, Bärbel, Jamieson, Rebecca A., Kontak, Daniel J., Koller, Friedrich, Leal Gomes, Carlos, London, David, Morgan, George B. VI, Neves, Luis J.P.F., Pattison, David R.M., Pereira, Alcides J.S.C., Pichavant, Michael, Rapela, Carlos W., Renno, Axel D., Richards, Simon, Roberts, Malcolm, Rottura, Alessandro, Saavedra, Julio, Sial, Alcides Nobrega, Toselli, Alejandro J., Ugidos, Jose M., Uher, Pavel, Villaseca González, Carlos, Visonà, Dario, Whitney, Donna L., Whilliamson, Ben, Woodard, Henry H.
Tipo de documento: artigo
Data de publicação:2005
País:España
Recursos:Universidad Complutense de Madrid (UCM)
Repositório:Docta Complutense
Idioma:inglês
OAI Identifier:oai:docta.ucm.es:20.500.14352/49592
Acesso em linha:https://hdl.handle.net/20.500.14352/49592
Access Level:Acceso aberto
Palavra-chave:552.3
Andalusite
Granite
Magmatic
Origin
Xenocrystic
Petrología
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network_acronym_str ES
network_name_str España
repository_id_str
dc.title.none.fl_str_mv Occurrence and Origin of Andalusite in Peraluminous Felsic Igneous Rocks
title Occurrence and Origin of Andalusite in Peraluminous Felsic Igneous Rocks
spellingShingle Occurrence and Origin of Andalusite in Peraluminous Felsic Igneous Rocks
Clarke, D. Barrie
552.3
Andalusite
Granite
Magmatic
Origin
Xenocrystic
Petrología
title_short Occurrence and Origin of Andalusite in Peraluminous Felsic Igneous Rocks
title_full Occurrence and Origin of Andalusite in Peraluminous Felsic Igneous Rocks
title_fullStr Occurrence and Origin of Andalusite in Peraluminous Felsic Igneous Rocks
title_full_unstemmed Occurrence and Origin of Andalusite in Peraluminous Felsic Igneous Rocks
title_sort Occurrence and Origin of Andalusite in Peraluminous Felsic Igneous Rocks
dc.creator.none.fl_str_mv Clarke, D. Barrie
Dorais, Michael
Barbarin, Bernard
Barker, Dan
Cesare, Bernardo
Clarke, Geoffrey
El Baghdadi, Mohamed
Erdmann, Saskia
Förster, Hans Jürger
Gaeta, Mario
Gottesmann, Bärbel
Jamieson, Rebecca A.
Kontak, Daniel J.
Koller, Friedrich
Leal Gomes, Carlos
London, David
Morgan, George B. VI
Neves, Luis J.P.F.
Pattison, David R.M.
Pereira, Alcides J.S.C.
Pichavant, Michael
Rapela, Carlos W.
Renno, Axel D.
Richards, Simon
Roberts, Malcolm
Rottura, Alessandro
Saavedra, Julio
Sial, Alcides Nobrega
Toselli, Alejandro J.
Ugidos, Jose M.
Uher, Pavel
Villaseca González, Carlos
Visonà, Dario
Whitney, Donna L.
Whilliamson, Ben
Woodard, Henry H.
author Clarke, D. Barrie
author_facet Clarke, D. Barrie
Dorais, Michael
Barbarin, Bernard
Barker, Dan
Cesare, Bernardo
Clarke, Geoffrey
El Baghdadi, Mohamed
Erdmann, Saskia
Förster, Hans Jürger
Gaeta, Mario
Gottesmann, Bärbel
Jamieson, Rebecca A.
Kontak, Daniel J.
Koller, Friedrich
Leal Gomes, Carlos
London, David
Morgan, George B. VI
Neves, Luis J.P.F.
Pattison, David R.M.
Pereira, Alcides J.S.C.
Pichavant, Michael
Rapela, Carlos W.
Renno, Axel D.
Richards, Simon
Roberts, Malcolm
Rottura, Alessandro
Saavedra, Julio
Sial, Alcides Nobrega
Toselli, Alejandro J.
Ugidos, Jose M.
Uher, Pavel
Villaseca González, Carlos
Visonà, Dario
Whitney, Donna L.
Whilliamson, Ben
Woodard, Henry H.
author_role author
author2 Dorais, Michael
Barbarin, Bernard
Barker, Dan
Cesare, Bernardo
Clarke, Geoffrey
El Baghdadi, Mohamed
Erdmann, Saskia
Förster, Hans Jürger
Gaeta, Mario
Gottesmann, Bärbel
Jamieson, Rebecca A.
Kontak, Daniel J.
Koller, Friedrich
Leal Gomes, Carlos
London, David
Morgan, George B. VI
Neves, Luis J.P.F.
Pattison, David R.M.
Pereira, Alcides J.S.C.
Pichavant, Michael
Rapela, Carlos W.
Renno, Axel D.
Richards, Simon
Roberts, Malcolm
Rottura, Alessandro
Saavedra, Julio
Sial, Alcides Nobrega
Toselli, Alejandro J.
Ugidos, Jose M.
Uher, Pavel
Villaseca González, Carlos
Visonà, Dario
Whitney, Donna L.
Whilliamson, Ben
Woodard, Henry H.
author2_role author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Universidad Complutense de Madrid
dc.subject.none.fl_str_mv 552.3
Andalusite
Granite
Magmatic
Origin
Xenocrystic
Petrología
topic 552.3
Andalusite
Granite
Magmatic
Origin
Xenocrystic
Petrología
description Andalusite occurs as an accessory mineral in many types of peraluminous felsic igneous rocks, including rhyolites, aplites, granites, pegmatites, and anatectic migmatites. Some published stability curves for And = Sil and the water-saturated granite solidus permit a small stability field for andalusite in equilibrium with felsic melts. We examine 108 samples of andalusite-bearing felsic rocks from more than 40 localities world-wide. Our purpose is to determine the origin of andalusite, including the T–P–X controls on andalusite formation, using eight textural and chemical criteria: size— compatibility with grain sizes of igneous minerals in the same rock; shape—ranging from euhedral to anhedral, with no simple correlation with origin; state of aggregation—single grains or clusters of grains; association with muscovite—with or without rims of monocrystalline or polycrystalline muscovite; inclusions—rare mineral inclusions and melt inclusions; chemical composition—andalusite with little significant chemical variation, except in iron content (0.08–1.71 wt % FeO); compositional zoning—concentric, sector, patchy, oscillatory zoning cryptically reflect growth conditions; compositions of coexisting phases—biotites with high siderophyllite– eastonite contents (Alw ≈ 268 ± 007 atoms per formula unit), muscovites with 0.57–4.01 wt % FeO and 0.02– 2.85 wt % TiO2, and apatites with 3.53 ± 0.18 wt % F. Coexisting muscovite–biotite pairs have a wide range of F contents, and FBt = 1.612FMs + 0015. Most coexisting minerals have compositions consistent with equilibration at magmatic conditions. The three principal genetic types of andalusite in felsic igneous rocks are: Type 1 Metamorphic—(a) prograde metamorphic (in thermally metamorphosed peraluminous granites), (b) retrograde metamorphic (inversion from sillimanite of unspecified origin) (c) xenocrystic (derivation from local country rocks), and (d) restitic (derivation from source regions); Type 2 Magmatic—(a) peritectic (water-undersaturated, T↑) associated with leucosomes in migmatites, (b) peritectic (water-undersaturated, T↓), as reaction rims on garnet or cordierite, (c) cotectic (water-undersaturated, T↓) direct crystallization from a silicate melt, and (d) pegmatitic (watersaturated, T↓), associated with aplite–pegmatite contacts or pegmatitic portion alone; Type 3 Metasomatic—(water-saturated, magma-absent), spatially related to structural discontinuities in host, replacement of feldspar and/or biotite, intergrowths with quartz. The great majority of our andalusite samples show one or more textural or chemical criteria suggesting a magmatic origin. Of the many possible controls on the formation of andalusite (excess Al2O3, water concentration and fluid evolution, high Be–B–Li–P, high F, high Fe–Mn–Ti, and kinetic considerations), the two most important factors appear to be excess Al2O3 and the effect of releasing water (either to strip alkalis from the melt or to reduce alumina solubility in the melt). Of particular importance is the evidence for magmatic andalusite in granites showing no significant depression of the solidus, suggesting that the And = Sil equilibrium must cross the granite solidus rather than lie below it. Magmatic andalusite, however formed, is susceptible to supra- or sub-solidus reaction to produce muscovite. In many cases, textural evidence of this reaction remains, but in other cases muscovite may completely replace
publishDate 2005
dc.date.none.fl_str_mv 2005
2005-01-01
2005
2005-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/20.500.14352/49592
url https://hdl.handle.net/20.500.14352/49592
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Oxford University Press
publisher.none.fl_str_mv Oxford University Press
dc.source.none.fl_str_mv reponame:Docta Complutense
instname:Universidad Complutense de Madrid (UCM)
instname_str Universidad Complutense de Madrid (UCM)
reponame_str Docta Complutense
collection Docta Complutense
repository.name.fl_str_mv
repository.mail.fl_str_mv
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spelling Occurrence and Origin of Andalusite in Peraluminous Felsic Igneous RocksClarke, D. BarrieDorais, MichaelBarbarin, BernardBarker, DanCesare, BernardoClarke, GeoffreyEl Baghdadi, MohamedErdmann, SaskiaFörster, Hans JürgerGaeta, MarioGottesmann, BärbelJamieson, Rebecca A.Kontak, Daniel J.Koller, FriedrichLeal Gomes, CarlosLondon, DavidMorgan, George B. VINeves, Luis J.P.F.Pattison, David R.M.Pereira, Alcides J.S.C.Pichavant, MichaelRapela, Carlos W.Renno, Axel D.Richards, SimonRoberts, MalcolmRottura, AlessandroSaavedra, JulioSial, Alcides NobregaToselli, Alejandro J.Ugidos, Jose M.Uher, PavelVillaseca González, CarlosVisonà, DarioWhitney, Donna L.Whilliamson, BenWoodard, Henry H.552.3AndalusiteGraniteMagmaticOriginXenocrysticPetrologíaAndalusite occurs as an accessory mineral in many types of peraluminous felsic igneous rocks, including rhyolites, aplites, granites, pegmatites, and anatectic migmatites. Some published stability curves for And = Sil and the water-saturated granite solidus permit a small stability field for andalusite in equilibrium with felsic melts. We examine 108 samples of andalusite-bearing felsic rocks from more than 40 localities world-wide. Our purpose is to determine the origin of andalusite, including the T–P–X controls on andalusite formation, using eight textural and chemical criteria: size— compatibility with grain sizes of igneous minerals in the same rock; shape—ranging from euhedral to anhedral, with no simple correlation with origin; state of aggregation—single grains or clusters of grains; association with muscovite—with or without rims of monocrystalline or polycrystalline muscovite; inclusions—rare mineral inclusions and melt inclusions; chemical composition—andalusite with little significant chemical variation, except in iron content (0.08–1.71 wt % FeO); compositional zoning—concentric, sector, patchy, oscillatory zoning cryptically reflect growth conditions; compositions of coexisting phases—biotites with high siderophyllite– eastonite contents (Alw ≈ 268 ± 007 atoms per formula unit), muscovites with 0.57–4.01 wt % FeO and 0.02– 2.85 wt % TiO2, and apatites with 3.53 ± 0.18 wt % F. Coexisting muscovite–biotite pairs have a wide range of F contents, and FBt = 1.612FMs + 0015. Most coexisting minerals have compositions consistent with equilibration at magmatic conditions. The three principal genetic types of andalusite in felsic igneous rocks are: Type 1 Metamorphic—(a) prograde metamorphic (in thermally metamorphosed peraluminous granites), (b) retrograde metamorphic (inversion from sillimanite of unspecified origin) (c) xenocrystic (derivation from local country rocks), and (d) restitic (derivation from source regions); Type 2 Magmatic—(a) peritectic (water-undersaturated, T↑) associated with leucosomes in migmatites, (b) peritectic (water-undersaturated, T↓), as reaction rims on garnet or cordierite, (c) cotectic (water-undersaturated, T↓) direct crystallization from a silicate melt, and (d) pegmatitic (watersaturated, T↓), associated with aplite–pegmatite contacts or pegmatitic portion alone; Type 3 Metasomatic—(water-saturated, magma-absent), spatially related to structural discontinuities in host, replacement of feldspar and/or biotite, intergrowths with quartz. The great majority of our andalusite samples show one or more textural or chemical criteria suggesting a magmatic origin. Of the many possible controls on the formation of andalusite (excess Al2O3, water concentration and fluid evolution, high Be–B–Li–P, high F, high Fe–Mn–Ti, and kinetic considerations), the two most important factors appear to be excess Al2O3 and the effect of releasing water (either to strip alkalis from the melt or to reduce alumina solubility in the melt). Of particular importance is the evidence for magmatic andalusite in granites showing no significant depression of the solidus, suggesting that the And = Sil equilibrium must cross the granite solidus rather than lie below it. Magmatic andalusite, however formed, is susceptible to supra- or sub-solidus reaction to produce muscovite. In many cases, textural evidence of this reaction remains, but in other cases muscovite may completely replaceOxford University PressUniversidad Complutense de Madrid20052005-01-0120052005-01-01journal articlehttp://purl.org/coar/resource_type/c_6501info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/20.500.14352/49592reponame:Docta Complutenseinstname:Universidad Complutense de Madrid (UCM)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2info:eu-repo/semantics/openAccessoai:docta.ucm.es:20.500.14352/495922026-06-02T12:44:21Z
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