Supramolecular self-sorting predicted by a simple harmonic oscillator model

Producción Científica

Detalhes bibliográficos
Autores: Sacristán Martín, Adriana, Álvarez Llorente, Nerea, Masson, Eric, Diez De La Varga, Alberto, Barbero San Juan, Héctor
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2024
País:España
Recursos:Universidad de Valladolid
Repositorio:UVaDOC. Repositorio Documental de la Universidad de Valladolid
OAI Identifier:oai:uvadoc.uva.es:10324/75058
Acesso em linha:https://doi.org/10.1039/D4CC05336B
https://uvadoc.uva.es/handle/10324/75058
Access Level:acceso abierto
Palavra-chave:2303 Química Inorgánica
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spelling Supramolecular self-sorting predicted by a simple harmonic oscillator modelSacristán Martín, AdrianaÁlvarez Llorente, NereaMasson, EricDiez De La Varga, AlbertoBarbero San Juan, Héctor2303 Química InorgánicaProducción CientíficaMacrocycles that encapsulate two guests can self-sort those into homo- and heterodimers. We report here a family of self-sorting homobimetallic Pt(II) terpyridyl acetylide dimers secured together with a pair of Cucurbit[8]uril macrocycles (CB[8]). The rigid bridging unit between both Pt centers introduces varying “hinge” angles, resulting in disparities in Pt–Pt distances in the heterodimers, and leads to recognition motif mismatch. We found that the self-sorting process can be quantified using a simple model, in which each complex behaves as a simple harmonic oscillator, whose heteroassembly tends to minimize geometry distorsions through C(aryl)–C[triple bond, length as m-dash]C–Pt axis deformation.Ministerio de Ciencia e Innovación (PID2021-124691NB-I00)National Science Foundation (CHE-1507321, CHE-1905238)American Chemical Society Petroleum Research Fund (56375-ND4)Unión Europea-NextGenerationEU (María Zambrano CONVREC-2021-264)Fundación Ramón Areces (contrato posdoctoral)Universidad de Valladolid-Banco Santander (contrato predoctoral)Royal Society of Chemistry2024info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://doi.org/10.1039/D4CC05336Bhttps://uvadoc.uva.es/handle/10324/75058reponame:UVaDOC. Repositorio Documental de la Universidad de Valladolidinstname:Universidad de ValladolidIngléshttps://pubs.rsc.org/en/content/articlelanding/2024/cc/d4cc05336binfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc/3.0/oai:uvadoc.uva.es:10324/750582026-06-13T12:44:47Z
dc.title.none.fl_str_mv Supramolecular self-sorting predicted by a simple harmonic oscillator model
title Supramolecular self-sorting predicted by a simple harmonic oscillator model
spellingShingle Supramolecular self-sorting predicted by a simple harmonic oscillator model
Sacristán Martín, Adriana
2303 Química Inorgánica
title_short Supramolecular self-sorting predicted by a simple harmonic oscillator model
title_full Supramolecular self-sorting predicted by a simple harmonic oscillator model
title_fullStr Supramolecular self-sorting predicted by a simple harmonic oscillator model
title_full_unstemmed Supramolecular self-sorting predicted by a simple harmonic oscillator model
title_sort Supramolecular self-sorting predicted by a simple harmonic oscillator model
dc.creator.none.fl_str_mv Sacristán Martín, Adriana
Álvarez Llorente, Nerea
Masson, Eric
Diez De La Varga, Alberto
Barbero San Juan, Héctor
author Sacristán Martín, Adriana
author_facet Sacristán Martín, Adriana
Álvarez Llorente, Nerea
Masson, Eric
Diez De La Varga, Alberto
Barbero San Juan, Héctor
author_role author
author2 Álvarez Llorente, Nerea
Masson, Eric
Diez De La Varga, Alberto
Barbero San Juan, Héctor
author2_role author
author
author
author
dc.subject.none.fl_str_mv 2303 Química Inorgánica
topic 2303 Química Inorgánica
description Producción Científica
publishDate 2024
dc.date.none.fl_str_mv 2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://doi.org/10.1039/D4CC05336B
https://uvadoc.uva.es/handle/10324/75058
url https://doi.org/10.1039/D4CC05336B
https://uvadoc.uva.es/handle/10324/75058
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv https://pubs.rsc.org/en/content/articlelanding/2024/cc/d4cc05336b
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc/3.0/
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc/3.0/
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:UVaDOC. Repositorio Documental de la Universidad de Valladolid
instname:Universidad de Valladolid
instname_str Universidad de Valladolid
reponame_str UVaDOC. Repositorio Documental de la Universidad de Valladolid
collection UVaDOC. Repositorio Documental de la Universidad de Valladolid
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