Direct, Copper-Catalyzed Oxidation of Aromatic C-H Bonds with Hydrogen Peroxide under Acid-Free Conditions
The direct oxidation of benzene into phenol using hydrogen peroxide has been achieved in the absence of any acid with TpxCu(NCMe) complexes as the catalysts. In the case of anthracenes as the substrates, valuable anthraquinones have been quantitatively obtained in the same manner
| Autores: | , , |
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| Formato: | artículo |
| Fecha de publicación: | 2011 |
| País: | España |
| Recursos: | Universidad de Huelva (UHU) |
| Repositorio: | Arias Montano. Repositorio Institucional de la Universidad de Huelva |
| Idioma: | inglés |
| OAI Identifier: | oai:ariasmontano.uhu.es:10272/11559 |
| Acesso em linha: | http://hdl.handle.net/10272/11559 |
| Access Level: | acceso abierto |
| Palavra-chave: | Benzene oxidation Copper catalysis C-H activation |
| Resumo: | The direct oxidation of benzene into phenol using hydrogen peroxide has been achieved in the absence of any acid with TpxCu(NCMe) complexes as the catalysts. In the case of anthracenes as the substrates, valuable anthraquinones have been quantitatively obtained in the same manner |
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