Microstructure and electrochemical behavior of AZ91 Mg Alloy produced by laser powder bed fusion

The corrosion behavior of the laser powder bed fusion (LPBF) AZ91 magnesium alloy was investigated by comparing its longitudinal and transverse sections with the cast AZ91 alloy. Microstructural analysis revealed a fine, homogeneous Mg<inf>17</inf>Al<inf>12</inf> distribution...

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Detalhes bibliográficos
Autores: Reyes-Riverol, R., Callaghan, G., García-Galván, F. R., Triviño Pélaez, Ángel, Medina, Judit, Williams, G., Jiménez, José Antonio, Fajardo, Santiago
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2025
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/402604
Acesso em linha:http://hdl.handle.net/10261/402604
https://api.elsevier.com/content/abstract/scopus_id/105016874188
Access Level:acceso abierto
Palavra-chave:Additive manufacturing
Selective laser melting
Mg alloys
AZ91
Microstructure
Corrosion resistance
Hydrogen evolution
Descrição
Resumo:The corrosion behavior of the laser powder bed fusion (LPBF) AZ91 magnesium alloy was investigated by comparing its longitudinal and transverse sections with the cast AZ91 alloy. Microstructural analysis revealed a fine, homogeneous Mg<inf>17</inf>Al<inf>12</inf> distribution in LPBF samples, contrasting with the network-like structure in the cast alloy. Electrochemical and hydrogen evolution tests demonstrated no significant anisotropy in LPBF sections, but they exhibited higher corrosion rates than the cast alloy. Potentiodynamic polarization and electrochemical impedance spectroscopy confirmed that the corrosion process was cathodically controlled by the Mg<inf>17</inf>Al<inf>12</inf> phase fraction. Scanning vibrating electrode technique further validated these findings, highlighting lower electrochemical activity in cast AZ91 alloy.