Perovskite FA1-xMAxPbI3 for solar cells: films formation and properties

[EN] Organic-inorganic hybrid perovskite formamidinium lead triiodide NH2CHNH2PbI3 (FAPbI3), methylammonium lead triiodide CH3NH3PbI3 (MAPbI3) and formamidinium methylammonium lead triiodide (NH2CHNH2)1-x(CH3NH2)xPbI3 (FA1-xMAxPbI3) thin films were synthesized and deposited on indium tin oxide glass...

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Authors: Slimi, B., Ben Assaker, I., Kriaa, A., Chtourou, R., Mollar García, Miguel Alfonso|||0000-0003-4315-0407, Marí, B.|||0000-0003-0001-419X
Format: article
Publication Date:2016
Country:España
Institution:Universitat Politècnica de València (UPV)
Repository:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Language:English
OAI Identifier:oai:riunet.upv.es:10251/120350
Online Access:https://riunet.upv.es/handle/10251/120350
Access Level:Open access
Keyword:Organic-inorganic perovskites
Formamidinium Lead Iodide
Planar heterojunction
Morphology control
Optical absorption
Photoluminescence.
FISICA APLICADA
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spelling Perovskite FA1-xMAxPbI3 for solar cells: films formation and propertiesSlimi, B.Ben Assaker, I.Kriaa, A.Chtourou, R.Mollar García, Miguel Alfonso|||0000-0003-4315-0407Marí, B.|||0000-0003-0001-419XOrganic-inorganic perovskitesFormamidinium Lead IodidePlanar heterojunctionMorphology controlOptical absorptionPhotoluminescence.FISICA APLICADA[EN] Organic-inorganic hybrid perovskite formamidinium lead triiodide NH2CHNH2PbI3 (FAPbI3), methylammonium lead triiodide CH3NH3PbI3 (MAPbI3) and formamidinium methylammonium lead triiodide (NH2CHNH2)1-x(CH3NH2)xPbI3 (FA1-xMAxPbI3) thin films were synthesized and deposited on indium tin oxide glass substrates by spin coating process. Thin films of mixed FA1-xMAxPbI3 (x = 0-1) perovskites obtained by mixing FAPbI3 and MAPbI3 in different proportions. The morphological, structural and optical proprieties of all synthetized perovskites have been analyzed as a function of the MA/FA ratio. X-ray diffraction analyses indicated the formation a cubic perovskite phase with space group Pm-3m in the composition range 0 ¿ x ¿ 1. Mixed perovskites FAMAPbI3 showed a high absorbance in the infrared region 780-900 nm. The band gap energy estimated from absorbance spectral measurements for FAMAPbI3 thin films ranges from 1.50 eV for FAPbI3 to 1.56 eV for MAPbI3, respectively. The overall PL emissions of mixed FA/MA perovskite thin films are located in intermediate values between 773 nm and 810 nm.This work was supported by Ministerio de Economia y Competitividad (ENE2013-46624-C4-4-R) and Generalitat valenciana (Prometeus 2014/044).ElsevierDepartamento de Física AplicadaEscuela Técnica Superior de Ingeniería Aeroespacial y Diseño IndustrialInstituto de Diseño para la Fabricación y Producción AutomatizadaGeneralitat ValencianaMinisterio de Economía, Industria y CompetitividadRepositorio Institucional de la Universitat Politècnica de València Riunet20162016-01-01journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://riunet.upv.es/handle/10251/120350reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengMinisterio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 ENE2013-46624-C4-4-R MEJORA DE LA CONVERSION DE ENERGIA SOLAR MEDIANTE PROCESOS DE EXCITACION ELECTRONICA EN DOS ETAPAS. APROXIMACION ELECTROQUIMICA.Generalitat Valenciana https://doi.org/10.13039/501100003359 PROMETEOII%2F2014%2F044 Técnicas de Fabricación Avanzada y Control de Calidad de nuevos materiales multifuncionales en movilidad sostenibleopen accesshttp://purl.org/coar/access_right/c_abf2Reconocimiento - Sin obra derivada (by-nd) http://creativecommons.org/licenses/by-nd/4.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/1203502026-06-13T07:49:27Z
dc.title.none.fl_str_mv Perovskite FA1-xMAxPbI3 for solar cells: films formation and properties
title Perovskite FA1-xMAxPbI3 for solar cells: films formation and properties
spellingShingle Perovskite FA1-xMAxPbI3 for solar cells: films formation and properties
Slimi, B.
Organic-inorganic perovskites
Formamidinium Lead Iodide
Planar heterojunction
Morphology control
Optical absorption
Photoluminescence.
FISICA APLICADA
title_short Perovskite FA1-xMAxPbI3 for solar cells: films formation and properties
title_full Perovskite FA1-xMAxPbI3 for solar cells: films formation and properties
title_fullStr Perovskite FA1-xMAxPbI3 for solar cells: films formation and properties
title_full_unstemmed Perovskite FA1-xMAxPbI3 for solar cells: films formation and properties
title_sort Perovskite FA1-xMAxPbI3 for solar cells: films formation and properties
dc.creator.none.fl_str_mv Slimi, B.
Ben Assaker, I.
Kriaa, A.
Chtourou, R.
Mollar García, Miguel Alfonso|||0000-0003-4315-0407
Marí, B.|||0000-0003-0001-419X
author Slimi, B.
author_facet Slimi, B.
Ben Assaker, I.
Kriaa, A.
Chtourou, R.
Mollar García, Miguel Alfonso|||0000-0003-4315-0407
Marí, B.|||0000-0003-0001-419X
author_role author
author2 Ben Assaker, I.
Kriaa, A.
Chtourou, R.
Mollar García, Miguel Alfonso|||0000-0003-4315-0407
Marí, B.|||0000-0003-0001-419X
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Departamento de Física Aplicada
Escuela Técnica Superior de Ingeniería Aeroespacial y Diseño Industrial
Instituto de Diseño para la Fabricación y Producción Automatizada
Generalitat Valenciana
Ministerio de Economía, Industria y Competitividad
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv Organic-inorganic perovskites
Formamidinium Lead Iodide
Planar heterojunction
Morphology control
Optical absorption
Photoluminescence.
FISICA APLICADA
topic Organic-inorganic perovskites
Formamidinium Lead Iodide
Planar heterojunction
Morphology control
Optical absorption
Photoluminescence.
FISICA APLICADA
description [EN] Organic-inorganic hybrid perovskite formamidinium lead triiodide NH2CHNH2PbI3 (FAPbI3), methylammonium lead triiodide CH3NH3PbI3 (MAPbI3) and formamidinium methylammonium lead triiodide (NH2CHNH2)1-x(CH3NH2)xPbI3 (FA1-xMAxPbI3) thin films were synthesized and deposited on indium tin oxide glass substrates by spin coating process. Thin films of mixed FA1-xMAxPbI3 (x = 0-1) perovskites obtained by mixing FAPbI3 and MAPbI3 in different proportions. The morphological, structural and optical proprieties of all synthetized perovskites have been analyzed as a function of the MA/FA ratio. X-ray diffraction analyses indicated the formation a cubic perovskite phase with space group Pm-3m in the composition range 0 ¿ x ¿ 1. Mixed perovskites FAMAPbI3 showed a high absorbance in the infrared region 780-900 nm. The band gap energy estimated from absorbance spectral measurements for FAMAPbI3 thin films ranges from 1.50 eV for FAPbI3 to 1.56 eV for MAPbI3, respectively. The overall PL emissions of mixed FA/MA perovskite thin films are located in intermediate values between 773 nm and 810 nm.
publishDate 2016
dc.date.none.fl_str_mv 2016
2016-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/120350
url https://riunet.upv.es/handle/10251/120350
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Ministerio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 ENE2013-46624-C4-4-R MEJORA DE LA CONVERSION DE ENERGIA SOLAR MEDIANTE PROCESOS DE EXCITACION ELECTRONICA EN DOS ETAPAS. APROXIMACION ELECTROQUIMICA.
Generalitat Valenciana https://doi.org/10.13039/501100003359 PROMETEOII%2F2014%2F044 Técnicas de Fabricación Avanzada y Control de Calidad de nuevos materiales multifuncionales en movilidad sostenible
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento - Sin obra derivada (by-nd)
http://creativecommons.org/licenses/by-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento - Sin obra derivada (by-nd)
http://creativecommons.org/licenses/by-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.228081

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