Novel Approaches towards Highly Selective Self-Powered Gas Sensors

The prevailing design approaches of semiconductor gas sensors struggle to overcome most of their current limitations such as poor selectivity, and high power consumption. Herein, a new sensing concept based on devices that are capable of detecting gases without the need of any external power sources...

Descripción completa

Detalles Bibliográficos
Autores: Hoffmann, M.W.G., Casals, O., Gad, A.E., Mayrhofer, L., Fàbrega, C., Caccamo, L., Hernandez-Ramirez, F., Lilienkamp, G., Daum, W., Moseler, M., Shen, H., Waag, A., Prades, J.D.
Tipo de recurso: artículo
Fecha de publicación:2015
País:España
Institución:Universitat Politècnica de Catalunya (UPC)
Repositorio:UPCommons. Portal del coneixement obert de la UPC
Idioma:inglés
OAI Identifier:oai:upcommons.upc.edu:2117/102727
Acceso en línea:https://hdl.handle.net/2117/102727
https://dx.doi.org/10.1016/j.proeng.2015.08.752
Access Level:acceso abierto
Palabra clave:Catalyst selectivity
Chemical sensors
Electronic structure
Gas detectors
Gases
Interfaces (materials)
Ionization of gases
Semiconductor materials
Current limitation
Design approaches
High power consumption
Integrated gas sensors
Nano-devices
Selective detection
Self-powered
Semiconductor gas sensors
Àrees temàtiques de la UPC::Energies
Descripción
Sumario:The prevailing design approaches of semiconductor gas sensors struggle to overcome most of their current limitations such as poor selectivity, and high power consumption. Herein, a new sensing concept based on devices that are capable of detecting gases without the need of any external power sources required to activate interaction of gases with sensor or to generate the sensor read out signal. Based on the integration of complementary functionalities (namely; powering and sensing) in a singular nanostructure, self-sustained gas sensors will be demonstrated. Moreover, a rational methodology to design organic surface functionalization that provide high selectivity towards single gas species will also be discussed. Specifically, theoretical results, confirmed experimentally, indicate that precisely tuning of the sterical and electronic structure of sensor material/organic interfaces can lead to unprecedented selectivity values, comparable to those typical of bioselective processes. Finally, an integrated gas sensor that combine both the self-powering and selective detection strategies in one single device will also be presented. © 2015 Published by Elsevier Ltd.