Effect of potassium loading on basic properties of Ni/MgAl2O4 catalyst for CO2 reforming of methane

. Coke deposition is one of the key issues in the dry reforming of methane on Ni catalysts. In the present work, we investigate the effect of potassium addition for suppressing carbon deposition in the Dry Reforming of Methane. The results obtained demonstrated that potassium contents above 3 wt% pr...

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Detalhes bibliográficos
Autores: Azancot, Lola, Bobadilla, Luis F., Centeno, Miguel Ángel, Odriozola, José Antonio
Formato: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2021
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/251398
Acesso em linha:http://hdl.handle.net/10261/251398
Access Level:acceso abierto
Palavra-chave:Ni-K catalysts
Basicity properties
CO2 adsorption
Dry reforming of methane
Descrição
Resumo:. Coke deposition is one of the key issues in the dry reforming of methane on Ni catalysts. In the present work, we investigate the effect of potassium addition for suppressing carbon deposition in the Dry Reforming of Methane. The results obtained demonstrated that potassium contents above 3 wt% promote carbon gasification, favouring both Reverse Water Gas Shift and Boudouard reaction. Strong basic Mg-O-K sites are responsible for these reactions allowing the suppression of carbon deposits and allowing the stability of the catalyst