Imaging of Antiferroelectric Dark Modes in an Inverted Plasmonic Lattice

Plasmonic lattice nanostructures are of technological interest because of their capacity to manipulate light below the diffraction limit. Here, we present a detailed study of dark and bright modes in the visible and near-infrared energy regime of an inverted plasmonic honeycomb lattice by a combinat...

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Detalhes bibliográficos
Autores: Rodríguez Álvarez, Javier, Labarta, Amílcar, Idrobo, Juan Carlos, Dell'Anna, Rossana, Cian, Alessandro, Giubertoni, Damiano, Borrisé, Xavier, Guerrero, Albert, Pérez Murano, Francesc, Fraile Rodríguez, Arantxa, Batlle Gelabert, Xavier
Tipo de documento: artigo
Estado:Versão publicada
Data de publicação:2023
País:España
Recursos:Universidad de Barcelona
Repositório:Dipòsit Digital de la UB
OAI Identifier:oai:diposit.ub.edu:2445/206183
Acesso em linha:https://hdl.handle.net/2445/206183
Access Level:Acceso aberto
Palavra-chave:Espectroscòpia de pèrdua d'energia d'electrons
Plasmons
Nanoestructures
Electron energy loss spectroscopy
Plasmons (Physics)
Nanostructures
Descrição
Resumo:Plasmonic lattice nanostructures are of technological interest because of their capacity to manipulate light below the diffraction limit. Here, we present a detailed study of dark and bright modes in the visible and near-infrared energy regime of an inverted plasmonic honeycomb lattice by a combination of Au+ focused ion beam lithography with nanometric resolution, optical and electron spectroscopy, and finite-difference time-domain simulations. The lattice consists of slits carved in a gold thin film, exhibiting hotspots and a set of bright and dark modes. We proposed that some of the dark modes detected by electron energy-loss spectroscopy are caused by antiferroelectric arrangements of the slit polarizations with two times the size of the hexagonal unit cell. The plasmonic resonances take place within the 0.5−2 eV energy range, indicating that they could be suitable for a synergistic coupling with excitons in two-dimensional transition metal dichalcogenides materials or for designing nanoscale sensing platforms based on near-field enhancement over a metallic surface.