Replication data for "Dithienylethene-based photoswitchable phosphines for palladium-catalyzed Stille coupling reaction"
Raw data of research article "Dithienylethene-based photoswitchable phosphines for palladium-catalyzed Stille coupling reaction". This research paper describes two photoisomerizable phosphine ligands synthesized based on dithienylethenes whose electronic communication with strong electron-...
| Autores: | , , , , , |
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| Formato: | conjunto de datos |
| Fecha de publicación: | 2024 |
| País: | España |
| Recursos: | Consorci de Serveis Universitaris de Catalunya (CSUC) |
| Repositorio: | CORA.Repositori de Dades de Recerca |
| OAI Identifier: | oai:dnet:cora.rdr____::640185d2f17073414bcd83a9f18edbdb |
| Acesso em linha: | https://doi.org/10.34810/DATA1275 |
| Access Level: | acceso abierto |
| Palavra-chave: | Chemistry Dithienylethenes Phosphines Catalysis Photoswitch |
| Resumo: | Raw data of research article "Dithienylethene-based photoswitchable phosphines for palladium-catalyzed Stille coupling reaction". This research paper describes two photoisomerizable phosphine ligands synthesized based on dithienylethenes whose electronic communication with strong electron-withdrawing groups is switched on and off upon light irradiation. As a result, the σ-donating ability of these phosphines can be efficiently light-controlled. This behavior was transferred to palladium(II) catalytic complexes and exploited to photomodulate the reaction rate of a model Stille reaction. |
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