A FTIR study of the metal-support interactions and hydrogen spillover on Pd/TiO2 and Ni/TiO2
Nickel and palladium dispersed on titania support were submitted to reductive treatment, under hydrogen, at 200 and 500 ºC. After the reductive thermal treatment the materials were exposed to carbon monoxide (10 Torr) and analyzed in the infrared region. The increasing of the electronic density in t...
| Authors: | , , , |
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| Format: | article |
| Status: | Published version |
| Publication Date: | 2002 |
| Country: | Brasil |
| Institution: | Universidade Federal do Rio Grande do Sul (UFRGS) |
| Repository: | Repositório Institucional da UFRGS |
| Language: | English |
| OAI Identifier: | oai:www.lume.ufrgs.br:10183/23132 |
| Online Access: | http://hdl.handle.net/10183/23132 |
| Access Level: | Open access |
| Keyword: | Interação metal-suporte Espectroscopia : Infravermelho Monóxido de carbono Metal-support Infrared Titania Carbon monoxide Hydrogen spillover Palladium Nickel |
| Summary: | Nickel and palladium dispersed on titania support were submitted to reductive treatment, under hydrogen, at 200 and 500 ºC. After the reductive thermal treatment the materials were exposed to carbon monoxide (10 Torr) and analyzed in the infrared region. The increasing of the electronic density in the metallic d subshell, produced by the reductive thermal treatment, was monitored by the infrared stretching band shift of carbon monoxide adsorbed and it was interpreted as a consequence of the metal-support interactions. The highest effect was observed for Pd/TiO2 system. From the FTIR spectra was also observed that the hydrogen spillover was stronger on Pd/TiO2 than Ni/TiO2 system. |
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