Síntese, caracterização e atividade fotocatalítica de catalisadores nanoestruturados de TiO2 dopados com metais

Titanium dioxide nanostructured catalysts (nanotubes) doped with different metals (silver, gold, copper, palladium and zinc) were synthesized by the hydrothermal method in order to promote an increase in their photocatalytic activity under visible light. The catalysts were characterized by X-ray dif...

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Detalhes bibliográficos
Autores: Silva, William Leonardo da, Lansarin, Marla Azario, Moro, Celso Camilo
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2013
País:Brasil
Recursos:Universidade Federal do Rio Grande do Sul (UFRGS)
Repositorio:Repositório Institucional da UFRGS
Idioma:portugués
OAI Identifier:oai:www.lume.ufrgs.br:10183/72906
Acesso em linha:http://hdl.handle.net/10183/72906
Access Level:acceso abierto
Palavra-chave:Fotocatálise
Nanotubos
Photocatalysis
TiO2 nanotubes
Metal doped TiO2
Descrição
Resumo:Titanium dioxide nanostructured catalysts (nanotubes) doped with different metals (silver, gold, copper, palladium and zinc) were synthesized by the hydrothermal method in order to promote an increase in their photocatalytic activity under visible light. The catalysts were characterized by X-ray diffraction, diffuse reflectance spectroscopy, transmission electron microscopy and specific area and pore volume determination. The materialsf photocatalytic activity was evaluated by rhodamine B decomposition in a glass batch reactor. Under UV radiation, only nanotubes doped with palladium were more active than the TiO2 P25, but the samples doped with silver, palladium and gold exhibited better results than the undoped samples under visible light.