TiO2/PDMS nanocomposites for use on self-cleaning surfaces

In this study, polydimethylsiloxane (PDMS)/TiO2 nanocomposite was processed by the spray method. TiO2 nanoparticles were synthesized by microwave-assisted hydrothermal method. Varying the proportion of nanoparticles in 0%, 0.5% and 1% by weight, commercial TiO2 (P25) was used for comparison purposes...

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Bibliographic Details
Authors: Tavares, Marileide L.A., Santos, Amélia S.F., Santos, Ieda Maria Garcia dos, Silva, Manoel Rincón S., Delmonte, Maurício Roberto Bomio, Silva, Elson Longo da, Paskocimas, Carlos Alberto, Motta, Fabiana Villela da
Format: article
Status:Published version
Publication Date:2014
Country:Brasil
Institution:Universidade Federal do Rio Grande do Norte (UFRN)
Repository:Repositório Institucional da UFRN
Language:English
OAI Identifier:oai:repositorio.ufrn.br:123456789/32024
Online Access:https://repositorio.ufrn.br/handle/123456789/32024
Access Level:Open access
Keyword:Microwave
Nanoparticles
TiO2
Nanocomposites
Photocatalytic activity
Description
Summary:In this study, polydimethylsiloxane (PDMS)/TiO2 nanocomposite was processed by the spray method. TiO2 nanoparticles were synthesized by microwave-assisted hydrothermal method. Varying the proportion of nanoparticles in 0%, 0.5% and 1% by weight, commercial TiO2 (P25) was used for comparison purposes. The photocatalytic activity of nanocomposites impregnated with methylene blue was assessed by means of UV–visible spectroscopy. Changes in contact angle were analyzed before and after UV degradation tests. The effect of ultraviolet radiation on the chemical structure of the PDMS matrix was evaluated by Fourier transform infrared spectroscopy (FTIR). The results indicated that the addition of TiO2 nanoparticles in PDMS provides good photocatalytic properties in the decomposition of methylene blue, which is an important characteristic for the development of coatings for self-cleaning. For comparison purposes, commercial P25 was also used to investigate the photocatalytic activity